等级
reagent grade
质量水平
反应适用性
reagent type: reductant
bp
116-118 °C/1 mmHg (lit.)
密度
0.798 g/mL at 25 °C (lit.)
SMILES字符串
[H][Al](CC(C)C)CC(C)C
InChI
1S/2C4H9.Al.H/c2*1-4(2)3;;/h2*4H,1H2,2-3H3;;
InChI key
AZWXAPCAJCYGIA-UHFFFAOYSA-N
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相关类别
一般描述
二异丁基氢化铝通常用作有机合成中的还原剂。
应用
二异丁基氢化铝可用于以下实验方案：
- 作为醛类Tishchenko反应的促进剂。
- 将1,2-和1,3-二醇的亚苄基缩醛转化为二醇的相应单苄基醚。
- 以（S）-脯氨酸为原料制备一种新型手性还原剂，用于前手性酮的不对称还原。
包装
法律信息
Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B - Water-react 1
补充剂危害
WGK
nwg
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
Asymmetric reduction of prochiral keto esters with a chiral reducing agent prepared from tin (II) chloride, chiral diamine, and diisobutylaluminum hydride.
Mukaiyama T, et al.
Chemistry Letters (Jpn), 14(6), 813-816 (1985)
Tishchenko reactions of aldehydes promoted by diisobutylaluminum hydride and its application to the macrocyclic lactone formation.
Hon YS, et al.
Tetrahedron, 63(46), 11325-11340 (2007)
A facile cleavage of benzylidene acetals with diisobutylaluminum hydride.
Takano S, et al.
Chemistry Letters (Jpn), 12(10), 1593-1596 (1983)
Daisuke Ando et al.
Journal of agricultural and food chemistry, 66(39), 10154-10162 (2018-09-13)
The metabolic fate of a new fungicide, mandestrobin, labeled with 14C at the phenoxy or benzyl ring was examined in wheat after a single spray application at 300 g/ha. Mandestrobin penetrated into foliage over time, with both radiolabels showing similar
Reaction of diisobutylaluminum hydride with selected organic compounds containing representative functional groups
Yoon N M
The Journal of Organic Chemistry, 50(14), 2443-2450 (1985)
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