255165
三丁基甲基氯化铵 溶液
75 wt. % in H2O
别名:
甲基三丁基氯化铵 溶液
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关于此项目
线性分子式:
CH3N[CH3(CH2)3]3Cl
化学文摘社编号:
分子量:
235.84
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352116
MDL number:
reaction suitability
core: ammonium
concentration
75 wt. % in H2O
refractive index
n20/D 1.4682
bp
152 °C
density
0.964 g/mL at 25 °C
InChI
1S/C13H30N.ClH/c1-5-8-11-14(4,12-9-6-2)13-10-7-3;/h5-13H2,1-4H3;1H/q+1;/p-1
SMILES string
[Cl-].CCCC[N+](C)(CCCC)CCCC
InChI key
IPILPUZVTYHGIL-UHFFFAOYSA-M
vapor pressure
7.9 mmHg ( 25 °C)
Quality Level
assay
77.2%
form
liquid
General description
三丁基甲基氯化铵(TBMAC)是一种季铵盐，常用作各种有机合成反应的相转移催化剂。也用于制备离子液体。
Application
三丁基甲基氯化铵溶液可作为相转移催化剂，用于在KHSO5氧化剂存在下，经由环己酮的Baeyer-Villiger氧化反应合成ɛ-己内酯。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
New and efficient technique for the synthesis of ?-caprolactone using KHSO5 as an oxidising agent in the presence of a phase transfer catalyst
Baj S, et al.
Applied Catalysis A: General, 395(1-2), 49-52 (2011)
Enantioselective biocatalytic reduction of 2 H-1, 4-benzoxazines using imine reductases
Zumbra?gel N, et al.
The Journal of Organic Chemistry, 84(3), 1440-1447 (2018)
H Steen et al.
Journal of hepatology, 21(3), 308-314 (1994-09-01)
The effect of ethanol on the hepatic uptake of various cationic drugs was studied in isolated perfused rat livers, isolated rat hepatocytes and isolated rat liver mitochondria. In isolated rat hepatocytes and in isolated perfused rat livers, the uptake of
Soon-Sun Hong et al.
Archives of pharmacal research, 28(3), 330-334 (2005-04-19)
The effect of a new hepatoprotective agent, YH-439, on the hepatobiliary transport of a model organic cation (OC), TBuMA (tributylmethylammonium), was investigated. The area under the plasma concentration-time curve (AUC) from time zero to 4 h following iv administration of
H Steen et al.
Biochemical pharmacology, 45(4), 809-818 (1993-02-24)
The effects of several metabolic inhibitors on the uptake of tri-n-butylmethylammonium (TBuMA) were studied in isolated rat liver mitochondria, isolated rat hepatocytes and isolated perfused rat livers, in order to characterize further the mechanisms for carrier-mediated uptake and cellular accumulation
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