检测方案
99%
形式
solid
bp
121-123 °C/8 mmHg (lit.)
mp
36-38 °C (lit.)
溶解性
alcohol: soluble(lit.)
water: insoluble(lit.)
SMILES字符串
COc1cccc(c1)[N+]([O-])=O
InChI
1S/C7H7NO3/c1-11-7-4-2-3-6(5-7)8(9)10/h2-5H,1H3
InChI key
WGYFINWERLNPHR-UHFFFAOYSA-N
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一般描述
Photoinduced nucleophilic substitution reactions of 3-nitroanisole in the presence of OH− in mixtures of H2O and CH3CN and in the presence of OCH3− in CH3OH were investigated by nanosecond time-resolved absorption spectroscopy. 3-Nitroanisole undergoes photoreaction with n-butylamine to yield 3-nitrophenol. It forms a 1:1 inclusion complex with β-cyclodextrin in aqueous buffer solution at pH 12.
警示用语：
Warning
危险声明
预防措施声明
危险分类
Acute Tox. 4 Oral
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
Modification of an intermolecular photoreaction by cyclodextrin: the photohydroxylation of 3-nitroanisole.
Evans CH and Gunnlaugsson T.
Journal of Photochemistry and Photobiology A: Chemistry, 78(1), 57-62 (1994)
Spectroscopic and kinetic study of the photoinduced methoxy substitution of 3-nitroanisole and 3, 5-dinitroanisole.
Van Zeijl PHM, et al.
Journal of Photochemistry, 29(3), 415-433 (1985)
Nitrophenyl ethers as possible photoaffinity labels. The nucleophilic aromatic photosubstitution revisited.
Cervelo J., et al.
Tetrahedron Letters, 25(37), 4147-4150 (1984)
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