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About This Item
线性分子式:
(CH3S)3CH
CAS号:
分子量:
154.32
Beilstein:
1733825
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
98%
折射率
n20/D 1.577 (lit.)
沸点
102 °C/15 mmHg (lit.)
225-227 °C (lit.)
mp
16 °C (lit.)
密度
1.16 g/mL at 25 °C (lit.)
官能团
thioether
SMILES字符串
CSC(SC)SC
InChI
1S/C4H10S3/c1-5-4(6-2)7-3/h4H,1-3H3
InChI key
YFMZQCCTZUJXEB-UHFFFAOYSA-N
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一般描述
Tris(methylthio)methane is a carboxylic anion equivalent.
应用
Tris(methylthio)methane has been used in synthesis of:
- (−)-nephrosteranic acid and (−)-roccellaric acid
- (4R,5R)-5-({[1-(tert-butyl)-1,1-diphenylsilyl]oxy}methyl)4-[tri(methylthio)methyl]tetrahydro-furan-2-one
- terminal difluoromethylenes
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
186.8 °F - closed cup
闪点(°C)
86 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Claudia Mugnaini et al.
Bioorganic & medicinal chemistry, 11(3), 357-366 (2003-01-09)
Novel nucleoside analogues of both D and L enantiomeric series were prepared by coupling reaction between a 2',3'-dideoxy-3'-modified furanose moiety and four different nucleobases. Though in all cases anomeric mixtures of nucleosides were obtained, the presence of the sterically bulky
From ketones, aldehydes or alkyl halides to terminal 1, 1-difluoroolefins using BrF3.
Hagooly A and Rozen S.
Journal of Fluorine Chemistry, 126(8), 1239-1245 (2005)
Bin Mao et al.
Organic letters, 13(5), 948-951 (2011-01-28)
An efficient catalytic asymmetric synthesis of chiral γ-butenolides was developed based on the hetero-allylic asymmetric alkylation (h-AAA) in combination with ring closing metathesis (RCM). The synthetic potential of the h-AAA-RCM protocol was illustrated with the facile synthesis of (-)-whiskey lactone
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