所有图片(1)
别名:
1,3-Bis(1,1-dimethylethyl) propanedioate, 1,3-Di-tert-butyl propanedioate, Bis(1,1-dimethylethyl) malonate, di-tert-butyl propanedioate, tert-Butyl malonate
线性分子式:
(CH3)3COCOCH2COOC(CH3)3
CAS号:
分子量:
216.27
Beilstein:
1781766
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
检测方案
98%
形式
liquid
折射率
n20/D 1.418 (lit.)
bp
110-111 °C/22 mmHg (lit.)
mp
−7-−6 °C (lit.)
密度
0.966 g/mL at 25 °C (lit.)
SMILES字符串
CC(C)(C)OC(=O)CC(=O)OC(C)(C)C
InChI
1S/C11H20O4/c1-10(2,3)14-8(12)7-9(13)15-11(4,5)6/h7H2,1-6H3
InChI key
CLPHAYNBNTVRDI-UHFFFAOYSA-N
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应用
丙二酸二叔丁酯已被用于(+/−)-actinophyllic acid的全合成。它还被用作HfO2和ZrO2薄膜的金属有机化学气相沉积的前体。
WGK
WGK 3
闪点(°F)
192.2 °F
闪点(°C)
89 °C
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Connor L Martin et al.
Journal of the American Chemical Society, 132(13), 4894-4906 (2010-03-12)
Development of efficient sequences for the total syntheses of (+/-)-actinophyllic acid (rac-1) and (-)-actinophyllic acid (1) are described. The central step in these syntheses is the aza-Cope/Mannich reaction, which constructs the previously unknown hexacyclic ring system of actinophyllic acid in
Ramasamy Pothiraja et al.
Dalton transactions (Cambridge, England : 2003), (4)(4), 654-663 (2009-04-22)
New Hf and Zr malonate complexes have been synthesized by the reaction of metal amides with different malonate ligands (L = dimethyl malonate (Hdmml), diethyl malonate (Hdeml), di-tert-butyl malonate (Hdbml) and bis(trimethylsilyl) malonate (Hbsml)). Homoleptic eight-coordinated monomeric compounds of the
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