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Merck
CN

254339

Sigma-Aldrich

2-丁炔

99%

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别名:
二甲基乙炔, 巴豆炔
线性分子式:
CH3C≡CCH3
CAS号:
分子量:
54.09
Beilstein:
1361340
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽压

11.47 psi ( 20 °C)

质量水平

检测方案

99%

形式

liquid

折射率

n20/D 1.393 (lit.)

bp

27 °C (lit.)

mp

−32 °C (lit.)

密度

0.691 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

CC#CC

InChI

1S/C4H6/c1-3-4-2/h1-2H3

InChI key

XNMQEEKYCVKGBD-UHFFFAOYSA-N

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一般描述

目前已有人使用离子阱质谱法研究了芳香族N-甲基-吡啶-4-基自由基阳离子与2-丁炔的离子-分子反应

应用

2-丁炔已用于制备无THF的金属环丁烯复合物

象形图

FlameExclamation mark

警示用语:

Danger

危险分类

Eye Irrit. 2 - Flam. Liq. 1 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Eyeshields, Faceshields, Gloves

法规信息

危险化学品

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Living polymerization of 2-butyne using a well-characterized tantalum catalyst.
Wallace KC, et al.
Organometallics, 8(3), 644-654 (1989)
C J Kees-Jan Weststrate et al.
Nature communications, 11(1), 750-750 (2020-02-08)
Facile C-C bond formation is essential to the formation of long hydrocarbon chains in Fischer-Tropsch synthesis. Various chain growth mechanisms have been proposed previously, but spectroscopic identification of surface intermediates involved in C-C bond formation is scarce. We here show
Oleg G Salnikov et al.
Chemical science, 8(3), 2426-2430 (2017-04-30)
Mechanistic insight into the semihydrogenation of 1-butyne and 2-butyne on Cu nanoparticles supported on partially dehydroxylated silica (Cu/SiO
Aaron M Thomas et al.
The journal of physical chemistry letters, 9(12), 3340-3347 (2018-05-31)
The bimolecular gas phase reaction of ground-state silicon (Si; 3P) with dimethylacetylene (C4H6; X1A1g) was investigated under single collision conditions in a crossed molecular beams machine. Merged with electronic structure calculations, the data propose nonadiabatic reaction dynamics leading to the
Hongzhen Wang et al.
The journal of physical chemistry. A, 119(46), 11313-11319 (2015-10-23)
The state-selective photodissociation of diacetylene (C4H2) was studied in the wavelength range of 127.5-164.4 nm by high-resolution Rydberg H atom time-of-flight spectroscopy measurements. In the wavelength region, two Rydberg series nR and nR' were state-selectively excited using tunable vacuum-ultraviolet laser

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