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Merck
CN
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文件

254037

Sigma-Aldrich

氯化三苯基磷金(I)

≥99.9% trace metals basis

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别名:
(Ph3P)AuCl, 三苯基膦氯化金(I)
线性分子式:
[(C6H5)3P]AuCl
CAS号:
14243-64-2
分子量:
494.71
EC 号:
238-117-6
MDL编号:
MFCD00009588
UNSPSC代码:
12352300
PubChem化学物质编号:
24855348
NACRES:
NA.22

质量水平

100

检测方案

≥99.9% trace metals basis

形式

solid

反应适用性

core: gold
reagent type: catalyst

SMILES字符串

Cl[Au].c1ccc(cc1)P(c2ccccc2)c3ccccc3

InChI

1S/C18H15P.Au.ClH/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h1-15H;;1H/q;+1;/p-1

InChI key

IFPWCRBNZXUWGC-UHFFFAOYSA-M

相关类别

应用

金催化剂— 21世纪 ′淘金热′
在室温下通过5-exo-digonal 途径将O-炔丙基氨基甲酸酯环化为亚烷基新恶唑烷酮（alkylideneoxazolidinones ）的催化剂。在室温下也催化含环烯烃的烯炔的环化异构化，生成高度稠合的多环二烯。
该试剂可与助催化卤化物提取剂一起使用以激活 π-系统通过杂原子和碳亲核试剂进行加成。

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315,H319,H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

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Leseurre, L. et al.
Organic Letters, 9 (2007)
Sang Ick Lee et al.
The Journal of organic chemistry, 71(25), 9366-9372 (2006-12-02)
Gold(I)-catalyzed cyclization of enynes containing an olefinic cycle has been studied. The introduction of an olefinic ring instead of a terminal alkene in enynes dramatically increased the yield of the reaction. Enynes having an olefinic cycle were prepared by a
Elena Barreiro et al.
Journal of inorganic biochemistry, 102(2), 184-192 (2007-09-18)
The reaction of triphenylphosphinegold(I) chloride in ethanol in a 1:1 molar ratio with the 3-(aryl)-2-sulfanylpropenoic acids H(2)xspa [x: p=3-phenyl-, Clp=3-(2-chlorophenyl)-, -o-mp=3-(2-methoxyphenyl)-, -p-mp=3-(4-methoxyphenyl)-, -o-hp=3-(2-hydroxyphenyl)-, -p-hp=3-(4-hydroxyphenyl)-, diBr-o-hp=3-(3,5-dibromo-2-hydroxyphenyl)-, f=3-(2-furyl)-, t=3-(2-thienyl)-, -o-py=3-(2-pyridyl)-; spa=2-sulfanylpropenoato] gave compounds of the type [Au(PPh(3))(Hxspa)], which were isolated and characterized
Ming Zhang et al.
Molecules (Basel, Switzerland), 17(3), 2812-2822 (2012-03-08)
An efficient method for the synthesis of β-enaminones and β-enaminoesters using a combination of [(PPh(3))AuCl]/AgOTf as catalyst has been developed. The reaction between 1,3-dicarbonyl compounds and primary amines was carried out under solvent-free conditions with low catalyst loading in good
Synlett, 3309-3309 (2006)
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