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254037

Sigma-Aldrich

氯化三苯基磷金(I)

≥99.9% trace metals basis

别名:

(Ph3P)AuCl, 三苯基膦氯化金(I)

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25 EA
CN¥513.45

CN¥513.45

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25 EA
CN¥513.45

About This Item

线性分子式:
[(C6H5)3P]AuCl
CAS号:
14243-64-2
分子量:
494.71
EC 号:
238-117-6
MDL编号:
MFCD00009588
UNSPSC代码:
12161600
PubChem化学物质编号:
24855348
NACRES:
NA.22

CN¥513.45

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方案

≥99.9% trace metals basis

表单

solid

反应适用性

core: gold
reagent type: catalyst

SMILES字符串

Cl[Au].c1ccc(cc1)P(c2ccccc2)c3ccccc3

InChI

1S/C18H15P.Au.ClH/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h1-15H;;1H/q;+1;/p-1

InChI key

IFPWCRBNZXUWGC-UHFFFAOYSA-M

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Nalgene® dropper bottle with screw closure

Nalgene® dropper bottle with screw closure capacity 8 mL, natural bottle, assorted colors cap

B6930

Nalgene® dropper bottle with screw closure

Nalgene® dropper bottle with screw closure capacity 15 mL, colorless bottle, white cap

B6305

Nalgene® dropper bottle with screw closure

material

colorless bottle, low-density polyethylene cap

material

low-density polyethylene , round bottle, white bottle

material

low-density polyethylene , natural bottle, round bottle

material

colorless bottle, low-density polyethylene , polypropylene cap, round bottle

capacity

8 mL

capacity

8 mL

capacity

8 mL

capacity

15 mL

joint

Joints threaded neck (15)

joint

Joints threaded neck (15-415)

joint

Joints threaded neck (15)

joint

Joints threaded neck (15)

packaging

pack of 25 ea

packaging

pack of 25 ea

packaging

pack of 25 ea

packaging

pack of 25 ea

color

white cap

color

white cap

color

assorted colors cap

color

white cap

应用

金催化剂— 21世纪 ′淘金热′
在室温下通过5-exo-digonal 途径将O-炔丙基氨基甲酸酯环化为亚烷基新恶唑烷酮（alkylideneoxazolidinones ）的催化剂。[1]在室温下也催化含环烯烃的烯炔的环化异构化，生成高度稠合的多环二烯。[2]
该试剂可与助催化卤化物提取剂一起使用以激活 π-系统通过杂原子和碳亲核试剂进行加成。

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315,H319,H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

  • 技术规格说明书

    • 历史批次信息供参考:

    分析证书(COA)

    Lot/Batch Number
    MKCT7658
    MKCR5954
    MKCQ1674
    MKCN0652
    MKCJ6853

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    访问文档库

    Synlett, 3309-3309 (2006)
    Leseurre, L. et al.
    Organic Letters, 9 (2007)
    Elena Barreiro et al.
    Journal of inorganic biochemistry, 102(2), 184-192 (2007-09-18)
    The reaction of triphenylphosphinegold(I) chloride in ethanol in a 1:1 molar ratio with the 3-(aryl)-2-sulfanylpropenoic acids H(2)xspa [x: p=3-phenyl-, Clp=3-(2-chlorophenyl)-, -o-mp=3-(2-methoxyphenyl)-, -p-mp=3-(4-methoxyphenyl)-, -o-hp=3-(2-hydroxyphenyl)-, -p-hp=3-(4-hydroxyphenyl)-, diBr-o-hp=3-(3,5-dibromo-2-hydroxyphenyl)-, f=3-(2-furyl)-, t=3-(2-thienyl)-, -o-py=3-(2-pyridyl)-; spa=2-sulfanylpropenoato] gave compounds of the type [Au(PPh(3))(Hxspa)], which were isolated and characterized
    Ming Zhang et al.
    Molecules (Basel, Switzerland), 17(3), 2812-2822 (2012-03-08)
    An efficient method for the synthesis of β-enaminones and β-enaminoesters using a combination of [(PPh(3))AuCl]/AgOTf as catalyst has been developed. The reaction between 1,3-dicarbonyl compounds and primary amines was carried out under solvent-free conditions with low catalyst loading in good
    Sang Ick Lee et al.
    The Journal of organic chemistry, 71(25), 9366-9372 (2006-12-02)
    Gold(I)-catalyzed cyclization of enynes containing an olefinic cycle has been studied. The introduction of an olefinic ring instead of a terminal alkene in enynes dramatically increased the yield of the reaction. Enynes having an olefinic cycle were prepared by a
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