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Merck
CN

252778

Sigma-Aldrich

氯甲酸正己酯

97%

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别名:
氯甲酸己酯, 氯甲酸正己酯, 碳酰氯己酯
线性分子式:
ClCO2(CH2)5CH3
CAS号:
分子量:
164.63
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽压

0.06 psi ( 20 °C)

质量水平

检测方案

97%

形式

liquid

折射率

n20/D 1.424 (lit.)

bp

60-61 °C/7 mmHg (lit.)

密度

1.007 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

CCCCCCOC(Cl)=O

InChI

1S/C7H13ClO2/c1-2-3-4-5-6-10-7(8)9/h2-6H2,1H3

InChI key

KIWBRXCOTCXSSZ-UHFFFAOYSA-N

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应用

氯甲酸己酯已被用作以下检测的衍生试剂:
  • 固相微萃取和快速 GC-MS 分析法测定尿液和尿沉渣中的肌氨酸和 N-乙基甘氨酸
  • 气相色谱-四极杆离子阱质谱法测定尿液中苯甲酰芽子碱

象形图

Skull and crossbonesCorrosion

警示用语:

Danger

危险分类

Acute Tox. 3 Oral - Skin Corr. 1B

WGK

WGK 3

闪点(°F)

143.6 °F

闪点(°C)

62 °C

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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B J Hall et al.
Journal of forensic sciences, 44(3), 527-534 (1999-07-17)
A derivatization/solid phase microextraction (SPME) method for the determination of benzoylecgonine in urine was developed. The derivatization is conducted directly in 1 mL of urine while sonicating for 3 min with 12 microL of hexyl chloroformate and 70 microL of
Tomáš Hložek et al.
Journal of analytical toxicology, 40(9), 749-753 (2016-09-04)
A simple, sensitive and robust method for simultaneous determination of antiepileptic drugs (gabapentin, pregabalin and vigabatrin) in human serum using GC-MS was developed and validated for clinical toxicology purposes. This method employs an emerging class of derivatization agents - alkyl
F Bianchi et al.
Analytica chimica acta, 707(1-2), 197-203 (2011-10-27)
A fully automated, non invasive, rapid and high-throughput method for the direct determination of sarcosine and N-ethylglycine in urine and urinary sediments using hexyl chloroformate derivatization followed by direct immersion solid-phase micro extraction and fast gas chromatography-mass spectrometric analysis was

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