所有图片(2)
About This Item
线性分子式:
Al(C2H5)3
CAS号:
分子量:
114.16
Beilstein:
3587229
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
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应用
Triethylaluminum solution can be used:
- As a reagent in Alumino-Mannich reaction, where it reacts with iminium ion substrates for which the corresponding Petasis borono-Mannich reaction is unsuccessful.
- In the synthesis of macrocyclic binuclear aluminum complexes with efficient activities toward ring-opening polymerization of ε-caprolactone.
- To promote Claisen rearrangement of allyl vinyl ether derivatives along with the transfer of ethyl group to aldehydic carbon.
- As a reagent for copper-catalyzed asymmetric conjugate addition of alkenyl- and alkylalanes to α,β-unsaturated lactams.
- As a precursor to synthesize diethylaluminium cyanide, which is used as hydrocyanating reagent.
警示用语：
Danger
危险分类
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Self-heat. 2 - Skin Corr. 1A - STOT SE 3 - Water-react 1
靶器官
Respiratory system
补充剂危害
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
闪点(°F)
-0.4 °F - closed cup
闪点(°C)
-18 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
Binuclear aluminum complexes with amine?imine type ligands derived from 1, 3-benzenedialdehyde: synthesis, structures and their catalytic properties in ring-opening polymerization.
Wu C, et al.
Journal of Coordination Chemistry, 69(6), 1066-1075 (2016)
Hydrocyanation. IV. New hydrocyanation methods using hydrogen cyanide and an alkylaluminum, and an alkylaluminum cyanide.
Nagata W, et al.
Journal of the American Chemical Society, 94(13), 4635-4643 (1972)
An Alumino?Mannich Reaction of Organoaluminum Reagents, Silylated Amines, and Aldehydes.
Tarasewicz A, et al.
Chemistry?A European Journal , 24(23), 6071-6074 (2018)
Aliphatic Claisen rearrangement promoted by organoaluminium reagents.
Takai K, et al.
Bulletin of the Chemical Society of Japan, 57(2), 446-451 (1984)
Copper-Catalyzed Asymmetric Conjugate Addition of Alkenyl-and Alkylalanes to ?, ?-Unsaturated Lactams.
Cottet P, et al.
Organic Letters, 15(4), 828-831 (2013)
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