推荐产品
质量水平
方案
85%
表单
liquid
杂质
<15% hexamethyldisiloxane
折射率
n20/D 1.396 (lit.)
沸点
90-92 °C (lit.)
密度
0.851 g/mL at 25 °C (lit.)
SMILES字符串
C[Si](C)(C)N=C=O
InChI
1S/C4H9NOSi/c1-7(2,3)5-4-6/h1-3H3
InChI key
NIZHERJWXFHGGU-UHFFFAOYSA-N
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应用
三甲基硅基异氰酸酯用于：
- 异构金属-有机骨架-3 的合成后修饰
- 1-未取代-4-（二烷基氨基）咪唑啉-2-酮的合成
- 环戊二烯基铁 (CO) 2 或锰 (CO) 3 催化异氰酸酯转化成碳二亚胺
- 芳香烃 和醇的氨甲酰化
警示用语：
Danger
危险分类
Acute Tox. 3 Inhalation - Eye Irrit. 2 - Flam. Liq. 2 - Resp. Sens. 1 - Skin Sens. 1 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
23.0 °F - closed cup
闪点(°C)
-5 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
SiNCO+ and SiNCS+ and their neutral counterparts.
Srinivas R, et al.
Chemical Physics Letters, 316(3), 243-247 (2000)
Reactions of trimethylsilyl isocyanate and isothiocyanate with 3-(dialkylamino)-2H-azirines. A facile synthesis of 1-unsubstituted 4-(dialkylamino) imidazolin-2-ones and 4-(dialkylamino) imidazoline-2-thiones
Handke I, et al.
The Journal of Organic Chemistry, 53(22), 5298-5300 (1988)
Tetrahedron Letters, 48, 6002-6002 (2007)
J. Prakt. Chem./Chem.-Ztg., 335, 558-558 (1993)
S Manfredini et al.
Journal of medicinal chemistry, 37(15), 2401-2405 (1994-07-22)
As a continuation of previous studies on the synthesis and antitumor activity of geiparvarin analogues bearing a carbamate moiety in the alkyl side chain, a series of N-substituted [(E)-3-(4,5-dihydro-5,5-dimethyl-4-oxo-2-furanyl)-2- butenyl]carbamates (15a-f) were synthesized and tested with the objective to investigate
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