252514
2-氯乙基氯甲酸酯
97%
别名:
氯甲酸-2-氯乙基酯
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关于此项目
线性分子式:
ClCOOCH2CH2Cl
化学文摘社编号:
分子量:
142.97
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-982-4
Beilstein/REAXYS Number:
506639
MDL number:
产品名称
2-氯乙基氯甲酸酯, 97%
InChI key
SVDDJQGVOFZBNX-UHFFFAOYSA-N
InChI
1S/C3H4Cl2O2/c4-1-2-7-3(5)6/h1-2H2
SMILES string
ClCCOC(Cl)=O
vapor pressure
0.23 psi ( 20 °C)
assay
97%
form
liquid
refractive index
n20/D 1.446 (lit.)
bp
155-156 °C (lit.)
density
1.385 g/mL at 25 °C (lit.)
functional group
chloro
storage temp.
2-8°C
Quality Level
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Application
2-Chloroethyl chloroformate has been used in the synthesis of:
- (4S)-4-hydroxymethyl-N-[(αR)-α-methylbenzyl]-2-oxazolidinone
- propargyl dienamide (ll), a precursor of allenic dienamide
- (±)-7-(2-chloroethyloxycarbonyloxy)-6-(5-chloropyridin-2-yl)-6,7-dihydro-5H-pyrrolo-[3,4-b]-pyrazin-5-one
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Eye Dam. 1 - Skin Corr. 1B
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
158.0 °F - closed cup
flash_point_c
70 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
A new approach to pyrrolophenanthridone alkaloids via allene intramolecular cycloaddition: Total synthesis of Hippadine.
Hayakawa K, et al.
Tetrahedron Letters, 28(47), 5895-5898 (1987)
Asymmetric synthesis of the 4-hydroxymethyl-2-oxazolidinone from the serinol derivative and chloroformates.
Sugiyama S, et al.
Tetrahedron Letters, 40(42), 7489-7492 (1999)
Enzymatic resolution of new carbonate intermediates for the synthesis of (< i> S</i>)-(+)-zopiclone.
Solares LF, et al.
Tetrahedron Asymmetry, 13(23), 2577-2582 (2002)
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