蒸汽压
0.23 psi ( 20 °C)
质量水平
检测方案
97%
形式
liquid
折射率
n20/D 1.446 (lit.)
bp
155-156 °C (lit.)
密度
1.385 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
ClCCOC(Cl)=O
InChI
1S/C3H4Cl2O2/c4-1-2-7-3(5)6/h1-2H2
InChI key
SVDDJQGVOFZBNX-UHFFFAOYSA-N
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应用
2-Chloroethyl chloroformate has been used in the synthesis of:
- (4S)-4-hydroxymethyl-N-[(αR)-α-methylbenzyl]-2-oxazolidinone
- propargyl dienamide (ll), a precursor of allenic dienamide
- (±)-7-(2-chloroethyloxycarbonyloxy)-6-(5-chloropyridin-2-yl)-6,7-dihydro-5H-pyrrolo-[3,4-b]-pyrazin-5-one
警示用语：
Danger
危险声明
危险分类
Acute Tox. 3 Inhalation - Eye Dam. 1 - Skin Corr. 1B
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Enzymatic resolution of new carbonate intermediates for the synthesis of (< i> S</i>)-(+)-zopiclone.
Solares LF, et al.
Tetrahedron Asymmetry, 13(23), 2577-2582 (2002)
Asymmetric synthesis of the 4-hydroxymethyl-2-oxazolidinone from the serinol derivative and chloroformates.
Sugiyama S, et al.
Tetrahedron Letters, 40(42), 7489-7492 (1999)
A new approach to pyrrolophenanthridone alkaloids via allene intramolecular cycloaddition: Total synthesis of Hippadine.
Hayakawa K, et al.
Tetrahedron Letters, 28(47), 5895-5898 (1987)
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