等级
technical
质量水平
检测方案
≥97.0% (GC)
形式
solid
颜色
deep brown
折射率
n20/D 1.635 (lit.)
n20/D 1.635
bp
167-169 °C/25 mmHg (lit.)
mp
32 °C (lit.)
密度
1.18 g/mL at 25 °C (lit.)
SMILES字符串
ClCc1cccc2ccccc12
InChI
1S/C11H9Cl/c12-8-10-6-3-5-9-4-1-2-7-11(9)10/h1-7H,8H2
InChI key
XMWGTKZEDLCVIG-UHFFFAOYSA-N
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一般描述
Kinetics and dissociation mechanism of 1-(chloromethyl)naphthalene following 266nm photoexcitation has been studied. Intermolecular nucleophilic dearomatization of 1-chloromethyl naphthalene with various activated methylene compounds has been investigated.
警示用语：
Danger
危险声明
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
WGK
WGK 3
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
Bo Peng et al.
Organic letters, 13(19), 5402-5405 (2011-09-14)
Palladium-catalyzed nucleophilic dearomatization of chloromethyl naphthalene derivatives to produce ortho- or para-substituted carbocycles in satisfactory to excellent yields has been developed. The unprecedented dearomatization reactions proceeded smoothly under mild conditions via η(3)-benzylpalladium intermediates.
Formation kinetics and spectra of aromatic radicals in solution.
Kelley DF, et al.
The Journal of Physical Chemistry, 87(11), 1842-1843 (1983)
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