251615
二氯乙基铝 溶液
1.0 M in hexanes
别名:
Dichloro(ethyl)alumane solution
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关于此项目
线性分子式:
CH3CH2AlCl2
化学文摘社编号:
分子量:
126.95
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4123357
产品名称
二氯乙基铝 溶液, 1.0 M in hexanes
InChI
1S/C2H5.Al.2ClH/c1-2;;;/h1H2,2H3;;2*1H/q;+2;;/p-2
SMILES string
CC[Al](Cl)Cl
InChI key
UAIZDWNSWGTKFZ-UHFFFAOYSA-L
vapor pressure
5 mmHg ( 60 °C)
form
liquid
concentration
1.0 M in hexanes
density
0.729 g/mL at 25 °C
Quality Level
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Application
Ethylaluminum dichloride is a strong Lewis acid and a proton scavenger that can be used:
- To catalyze polymerization of isobutylene.
- To facilitate Diels-Alder reaction of α,β-unsaturated esters.
- To carry out Pinacol reduction rearrangements.
- To promote Schmidt rearrangement of diketoazides in the synthesis of indolizidines and pyrroloazepinediones.
signalword
Danger
Hazard Classifications
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 1 Inhalation - STOT SE 3 - Water-react 2
target_organs
Central nervous system, Nervous system
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
-9.4 °F - closed cup
flash_point_c
-23 °C - closed cup
法规信息
新产品
此项目有
Concise access to indolizidine and pyrroloazepine skeleta via intramolecular Schmidt reactions of azido 1, 3-diketones.
Lertpibulpanya D and Marsden S P
Organic & Biomolecular Chemistry, 4(18), 3498-3504 (2006)
Kinetic and Mechanistic Studies of the Polymerization of Isobutylene Catalyzed by EtAlCl2/Bis (2-chloroethyl) Ether Complex in Hexanes.
Banerjee S, et al.
Macromolecules, 48(16), 5474-5480 (2015)
Cyclorearrangement and cycloolefination of keto-bis-sulfones. A sulfone analog of a pinacol reduction-rearrangement.
Trost B M, et al.
Journal of the American Chemical Society, 114(13), 5432-5434 (1992)
Ethylaluminum Dichloride.
Snider B B.
e-EROS Encyclopedia of Reagents for Organic Synthesis (2001)
Stereochemical aspects of the intramolecular Diels-Alder reactions of methyl deca-2, 7, 9-trienoates. 1. Thermal cyclizations.
Roush W R, et al.
The Journal of Organic Chemistry, 45(21), 4264-4267 (1980)
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