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Merck
CN

250252

Sigma-Aldrich

1-萘甲酰氯

97%

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线性分子式:
C10H7COCl
CAS号:
分子量:
190.63
Beilstein:
775785
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

97%

形式

liquid

折射率

n20/D 1.652 (lit.)

bp

190 °C/35 mmHg (lit.)

mp

16-19 °C (lit.)

密度

1.265 g/mL at 25 °C (lit.)

SMILES字符串

ClC(=O)c1cccc2ccccc12

InChI

1S/C11H7ClO/c12-11(13)10-7-3-5-8-4-1-2-6-9(8)10/h1-7H

InChI key

NSNPSJGHTQIXDO-UHFFFAOYSA-N

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应用

1-萘酰氯已经被用于:
  • 作为固相萃取-分散液-液微萃取法分析短链十二烷基醇乙氧基化物和十二烷基醇的衍生化试剂
  • 作为高效液相色谱荧光检测法测定 T-2 和 HT-2 毒素的荧光标记试剂
  • 在三甲基硅基重氮甲烷存在的情况下进行 Arndt-Eistert 合成
  • 制备2-乙基-1-戊基-3-(1-萘甲酰)吲哚

象形图

Corrosion

警示用语:

Danger

危险声明

危险分类

Skin Corr. 1B

WGK

WGK 3

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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New methods and reagents in organic synthesis. 8. Trimethylsilyldiazomethane. A new, stable, and safe reagent for the classical arndt-eistert synthesis.
Aoyama T and Shioiri T.
Tetrahedron Letters, 21(46), 4461-4462 (1980)
John W Huffman et al.
Bioorganic & medicinal chemistry, 11(4), 539-549 (2003-01-23)
A series of 1-pentyl-1H-indol-3-yl-(1-naphthyl)methanes (9-11) and 2-methyl-1-pentyl-1H-indol-3-yl-(1-naphthyl)methanes (12-14) have been synthesized to investigate the hypothesis that cannabimimetic 3-(1-naphthoyl)indoles interact with the CB(1) receptor by hydrogen bonding to the carbonyl group. Indoles 9-11 have significant (K(i)=17-23nM) receptor affinity, somewhat less than
Vincenzo Lippolis et al.
Talanta, 74(5), 1476-1483 (2008-03-29)
T-2 and HT-2 toxins are Fusarium mycotoxins that can occur in cereals and cereal-based products. Three fluorescent labeling reagents, i.e. 1-naphthoyl chloride (1-NC), 2-naphthoyl chloride (2-NC) and pyrene-1-carbonyl cyanide (PCC), were used for the determination of T-2 and HT-2 toxins
Agnieszka Zgoła-Grześkowiak et al.
Journal of chromatography. A, 1251, 40-47 (2012-07-10)
A new method was developed for preconcentration, derivatisation and analysis of short-chained dodecyl alcohol ethoxylates and dodecyl alcohol. Solid-phase extraction combined with dispersive liquid-liquid microextraction was used for preconcentration of target compounds. Several parameters were optimised including different solid phase

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