质量水平
检测方案
95% (Purity of contained acetylide)
浓度
18 wt. % slurry in xylene: light mineral oil
SMILES字符串
[Na]C#C
InChI
1S/C2H.Na/c1-2;/h1H;
InChI key
SLBNQJAGYKQCKI-UHFFFAOYSA-N
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应用
乙酸钠混悬液用于制备：
- 2-乙炔基金刚烷-2-醇
- (Et4N)3[1-(2′) -B10H9)-2-NH3B10H8]的顶-赤道 (ae) 异构体
- 三甲基硅烷乙炔
警示用语：
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT RE 2 Inhalation - STOT SE 3 - Water-react 2
靶器官
Central nervous system,Liver,Kidney, Respiratory system
补充剂危害
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Synthesis of novel carbo-and hetero-polycycles. Part 8. An efficient and convenient synthesis of adamantylidenevinylidenecyclopropane derivatives.
Eguchi S and Arasaki M.
Journal of the Chemical Society. Perkin Transactions 1, 5, 1047-1050 (1988)
D A Feakes et al.
Proceedings of the National Academy of Sciences of the United States of America, 91(8), 3029-3033 (1994-04-12)
The polyhedral borane ion [n-B20H18]2- reacts with liquid ammonia in the presence of a suitable base to produce an apical-equatorial (ae) isomer of the [B20H17NH3]3- ion, [1-(2'-B10H9)-2-NH3B10H8]3-. The structure of this product has been confirmed by 11B NMR spectroscopy and
A new synthetic route to donor-acceptor porphyrins.
Plater MJ, et al.
Tetrahedron, 58(12), 2405-2413 (2002)
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