产品名称
6-溴-1-己烯, 95%
InChI
1S/C6H11Br/c1-2-3-4-5-6-7/h2H,1,3-6H2
SMILES string
BrCCCCC=C
InChI key
RIMXEJYJXDBLIE-UHFFFAOYSA-N
assay
95%
form
liquid
impurities
<3% DMF
refractive index
n20/D 1.465 (lit.)
bp
47-51 °C/16 mmHg (lit.)
density
1.22 g/mL at 25 °C (lit.)
functional group
alkyl halide
allyl
bromo
Quality Level
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Application
6-溴-1-己烯用于制备环氧化物,6-溴-1,2-环氧己烷 。它也被用于在液氨中通过对苯二甲腈的阴离子还原形式简单、直接地制备 4-烯基苯甲腈 。
General description
6-溴-1-己烯与镁反应生成格氏试剂 。已用 X 射线光电子能谱和程序升温脱附研究了 6-溴-1-己烯在 Ni (100) 表面的热化学。
signalword
Danger
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
129.2 °F - closed cup
flash_point_c
54 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
The formation of grignard compounds-III: The influence of the solvent.
Bodewitz HWHJ, et al.
Tetrahedron, 31(8), 1053-1063 (1975)
Thermal chemistry of 1, 6-diiodohexane on Ni (100) single-crystal surfaces: Mimicking cyclization reactions.
Tjandra S and Zaera F.
The Journal of Physical Chemistry A, 103(!4), 2312-2320 (1999)
Synlett, 1616-1616 (2007)
Cyclization of 6-bromo-1, 2-epoxyhexane promoted by metal-halogen exchange: unexpected regioselectivity.
Babler JH and Bauta WE.
Tetrahedron Letters, 25(39), 4323-4324 (1984)
Hiroshi Toda et al.
Applied and environmental microbiology, 81(6), 1919-1925 (2015-01-04)
We describe the development of biocatalysis for producing optically pure straight-chain (S)-epoxyalkanes using styrene monooxygenase of Rhodococcus sp. strain ST-10 (RhSMO). RhSMO was expressed in the organic solvent-tolerant microorganism Kocuria rhizophila DC2201, and the bioconversion reaction was performed in an
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