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Merck
CN

247197

Sigma-Aldrich

甲基乙烯基砜

≥97%

别名:

1-甲磺酰基乙烯, 乙烯基甲基砜, 甲基乙烯基砜, 甲磺酰乙烯, (甲磺酰基)乙烯

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About This Item

线性分子式:
H2C=CHSO2CH3
CAS号:
分子量:
106.14
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

检测方案

≥97%

形式

liquid

包含

0.02% p-tert-butylphenol as stabilizer

折射率

n20/D 1.463 (lit.)

bp

115-117 °C/19 mmHg (lit.)

密度

1.212 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

CS(=O)(=O)C=C

InChI

1S/C3H6O2S/c1-3-6(2,4)5/h3H,1H2,2H3

InChI key

WUIJTQZXUURFQU-UHFFFAOYSA-N

基因信息

应用

已使用甲基乙烯基砜:
  • 作为衍生化试剂的改进方法,使用毛细管 HPLC-质谱法测定核苷混合物中的假尿苷
  • 棉织物迈克尔加成法制备甲基磺酰基乙基纤维素
  • 卤代芳烃的赫克乙烯化

象形图

Skull and crossbonesCorrosion

警示用语:

Danger

危险声明

危险分类

Acute Tox. 2 Dermal - Acute Tox. 4 Oral - Eye Dam. 1

WGK

WGK 3

闪点(°F)

>235.4 °F

闪点(°C)

> 113 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Gert Emmerechts et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 825(2), 233-238 (2005-07-21)
A method is presented for improved detection of pseudouridine in nucleoside mixtures based on the specific derivatization with methyl vinyl sulfone followed by analysis by capillary HPLC-mass spectrometry. Reaction conditions were optimized in order to obtain the best yield and
G B Gordon et al.
Carcinogenesis, 12(12), 2393-2396 (1991-12-01)
The induction of quinone reductase [QR; NAD(P)H:(quinone acceptor) oxidoreductase; EC 1.6.99.2] in cultured cells and animal tissues of rodents has provided useful information on mechanisms of protection against carcinogens. We have developed a simple and efficient microtiter plate assay for
Synthesis, 3495-3495 (2006)
K L Dearfield et al.
Mutagenesis, 6(6), 519-525 (1991-11-01)
Over the past several years, we have been evaluating the mutagenicity and clastogenicity of compounds capable of Michael-type reactions. These compounds, including acrylamide, several acrylate and methacrylate esters, vinyl sulfones, and phorone, have been evaluated using TK+/- -3.7.2C mouse lymphoma
M S Masri et al.
Journal of protein chemistry, 7(1), 49-54 (1988-02-01)
Disulfide bonds of bovine serum albumin and wool were reduced by n-tributylphosphine to sulfhydryl groups that were then modified by methyl or ethyl vinyl sulfone in a nucleophilic addition reaction to S-(beta-ethylsulfonylmethyl)-L-cysteine and S(beta-ethylsulfonylethyl)-L-cysteine, respectively. The reductive alkylation was carried

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