247138
氯羰基亚磺酰氯
96%
别名:
(氯巯基)甲酰氯, 氯甲酰亚磺酰氯
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关于此项目
线性分子式:
ClCOSCl
化学文摘社编号:
分子量:
130.98
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
220-415-2
Beilstein/REAXYS Number:
506318
MDL number:
Assay:
96%
Form:
liquid
InChI key
MNOALXGAYUJNKX-UHFFFAOYSA-N
InChI
1S/CCl2OS/c2-1(4)5-3
SMILES string
ClSC(Cl)=O
assay
96%
form
liquid
refractive index
n20/D 1.517 (lit.)
bp
98 °C (lit.)
density
1.552 g/mL at 25 °C (lit.)
functional group
chloro
storage temp.
2-8°C
Quality Level
Application
氯羰基亚磺酰氯已用于制备：
- 5-(1,2,3,4-四-O-乙酰-α-D-吡喃木糖-5S-C-基)-1,3,4-氧杂噻唑-2-酮
- 氟化的oxathialones
- 聚氟烷基-硫代氯甲酸
- 氯羰基聚氟烷基次磺酸酯
- 氯羰基六氟异丙叉基亚氨次磺酸
- 5-三-氟甲基-2-氧代-1,3,4-氧杂噻唑
- 具有重要商业价值的N,N-二烷基氨甲酰氯化物
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
143.6 °F - closed cup
flash_point_c
62 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Some fluorinated heterocyclic and acyclic derivatives of chlorocarbonylsulfenyl chloride.
John EO and Jean'ne MS.
Journal of Fluorine Chemistry, 36(4), 429-438 (1987)
Keith G McMillan et al.
Carbohydrate research, 341(1), 41-48 (2005-11-03)
5-(1,2,3,4-tetra-O-acetyl-alpha-D-xylopyranos-5S-C-yl)-1,3,4-oxathiazol-2-one (8) has been prepared from glucuronamide in two steps and 73% overall yield by conversion to the tetra-O-acetyl derivative 7 followed by reaction with chlorocarbonylsulfenyl chloride. 5-(2,3,4-Tri-O-acetyl-beta-D-xylopyranosyl)-1,3,4-oxathiazol-2-one (12) was synthesised from D-xylose by a four-step sequence involving conversion to
An improved one-pot cost-effective synthesis of N, N-disubstituted carbamoyl halides and derivatives.
Adeppa K, et al.
Canadian Journal of Chemistry, 88(!2), 1277-1280 (2010)
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