检测方案
98%
形式
crystals
mp
131-133 °C (lit.)
SMILES字符串
BrCc1cccc2cccc(CBr)c12
InChI
1S/C12H10Br2/c13-7-10-5-1-3-9-4-2-6-11(8-14)12(9)10/h1-6H,7-8H2
InChI key
GCZOMCDXYFMAGP-UHFFFAOYSA-N
一般描述
Two-photon chemistry of 1,8-bis(bromomethyl)naphthalene has been studied by time-delayed, two-color photolysis and argon ion laser-jet photolysis techniques.
应用
1,8-Bis(bromomethyl)naphthalene has been used in the synthesis of indan-based unusual α-amino acid derivatives under solid-liquid phase-transfer catalysis conditions.
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
Two-Photon Laser-Induced Reaction of 1, 8-Bis (halomethyl) naphthalenes from Different Excited States and Transient Targeting of Its Intermediate by Time-Delayed, Two-Color Photolysis and Argon Ion Laser-Jet Photolysis Techniques
Ouchi A, et al.
Journal of the American Chemical Society, 119(3), 592-599 (1997)
S Kotha et al.
The Journal of organic chemistry, 65(5), 1359-1365 (2000-05-18)
Conformationally constrained cyclic alpha-amino acid derivatives were synthesized under solid-liquid phase-transfer catalysis conditions. This methodology involves the bis-alkylation of ethyl isocyanoacetate with various alpha,alpha'-dibromo-o-xylene derivatives [alpha,alpha'-dibromo-o-xylene 5, 2,3-bis(bromomethyl)-1, 4-dimethoxybenzene 6, 1,2-bis(bromomethyl)-4,5-dibromobenzene 7, 2, 3-bis(bromomethyl)naphthalene 8, 1,8-bis(bromomethyl)-naphthalene 9, 6,7-bis(bromomethyl)-2,2-dimethyl-1H-phenalene-1,3(2H)-dione 10, 2
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