246352
氨基甲酸甲酯
98%
别名:
尿基烷
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关于此项目
线性分子式:
NH2COOCH3
化学文摘社编号:
分子量:
75.07
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
209-939-2
MDL number:
Assay:
98%
Form:
crystals
产品名称
氨基甲酸甲酯, 98%
InChI key
GTCAXTIRRLKXRU-UHFFFAOYSA-N
InChI
1S/C2H5NO2/c1-5-2(3)4/h1H3,(H2,3,4)
SMILES string
COC(N)=O
assay
98%
form
crystals
bp
176-177 °C (lit.)
mp
56-58 °C (lit.)
solubility
alcohol: freely soluble(lit.)
water: freely soluble(lit.)
functional group
amine
Quality Level
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Application
氨基甲酸甲酯被用于合成受保护的氨基环丙烷。
signalword
Warning
hcodes
Hazard Classifications
Carc. 2 - Eye Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Shingo Ishikawa et al.
Angewandte Chemie (International ed. in English), 52(38), 10060-10063 (2013-08-06)
Easy as 1,2,3: Reaction of methyl carbamate, triethyl orthoformate, and readily available alkenes provides a highly practical preparation of protected aminocyclopropanes. The reaction proceeds with preferential cis addition to alkenes, and cleavage of the methyl carbamate gives the free aminocyclopropanes
Genotoxicity data supporting the proposed metabolic activation of ethyl carbamate (urethane) to a carcinogen: the problem now posed by methyl carbamate.
J Ashby
Mutation research, 260(4), 307-308 (1991-08-01)
Joshua A Hartsel et al.
Bioorganic & medicinal chemistry letters, 22(14), 4593-4598 (2012-06-29)
To identify potential human-safe insecticides against the malaria mosquito we undertook an investigation of the structure-activity relationship of aryl methylcarbamates inhibitors of acetylcholinesterase (AChE). Compounds bearing a β-branched 2-alkoxy or 2-thioalkyl group were found to possess good selectivity for inhibition
Xiangyun Lin et al.
Journal of separation science, 34(2), 202-209 (2011-01-20)
This paper described a simple, rapid and efficient method for the determination of N-methyl carbamate pesticides in tomato, cucumber, carrot and lettuce samples by dispersive liquid-liquid microextraction coupled with HPLC-diode array detection. Some experimental parameters that influenced the extraction efficiency
D F K Rawn et al.
Food additives and contaminants, 21(6), 555-563 (2004-06-19)
Infants and young children consume fruit juices and drinks at rates exceeding those of older children and adults. Carbamate pesticides are known to be used on a broad spectrum of crops, including orchard and vine crops such as apples and
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