246034
苄基三甲基氢氧化铵 溶液
40 wt. % in H2O
别名:
N,N,N-Trimethyl-N-benzylammonium hydroxide, N,N,N-trimethyl-1-phenylmethanaminium hydroxide, N,N,N-trimethylbenzenemethanaminium hydroxide, Triton B
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所有图片(1)
About This Item
线性分子式:
C6H5CH2N(OH)(CH3)3
CAS号:
分子量:
167.25
Beilstein:
3917256
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
浓度
40 wt. % in H2O
折射率
n20/D 1.43
密度
1.059 g/mL at 25 °C
官能团
amine
phenyl
SMILES字符串
[OH-].C[N+](C)(C)Cc1ccccc1
InChI
1S/C10H16N.H2O/c1-11(2,3)9-10-7-5-4-6-8-10;/h4-8H,9H2,1-3H3;1H2/q+1;/p-1
InChI key
NDKBVBUGCNGSJJ-UHFFFAOYSA-M
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一般描述
苄基三甲基氢氧化铵溶液可用作相转移催化剂。它有助于原位酯交换反应以合成生物柴油。
应用
苄基三甲基氢氧化铵可用于：
- 作为碱参与合成活化ynesulfonamide和叔enesulfonamide。
- 以吲哚处理靛红合成3-吲哚基-3-羟基羟吲哚。
- 作为前体制备乙酸季铵盐苄基三甲基乙酸铵（NBz111AcO）。NBz111AcO的DMSO溶液可用于溶解纤维素。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1A
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Triton B-Assisted, Efficient, and Convenient Synthesis of 3-Indolyl-3-hydroxy Oxindoles in Aqueous Medium
Meshram HM, et al.
Synthetic Communications, 40(1), 39-45 (2009)
Metal-Free Synthesis of Activated Ynesulfonamides and Teritary Enesulfonamides
Andna L and Miesch L
Organic & Biomolecular Chemistry (2019)
Parametric study and optimization of in situ transesterification of Jatropha curcas L assisted by benzyltrimethylammonium hydroxide as a phase transfer catalyst via response surface methodology
Hailegiorgis SM, et al.
Biomass and Bioenergy, 63-73}-63-73} (2013)
Dependence of cellulose dissolution in quaternary ammonium-based ionic liquids/DMSO on the molecular structure of the electrolyte
Kostag M and El Seoud OA
Carbohydrate Polymers, 205(1), 524-532 (2019)
Purushothaman Gopinath et al.
The Journal of organic chemistry, 74(16), 6291-6294 (2009-07-22)
An efficient protocol is reported for the synthesis of thioesters from carboxylic acids with use of acyloxy phosphonium salts as intermediates and benzyltriethylammonium tetrathiomolybdate as the sulfur transfer reagent.
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