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主要文件

245739

Sigma-Aldrich

4,4′-二甲基-2,2′-联吡啶

99%

别名:

2,2′-二(γ-甲基吡啶), 4,4′-二甲基-2,2′-二吡啶

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¥952.83
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¥2,998.12

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5 G
¥952.83
25 G
¥2,998.12

About This Item

经验公式(希尔记法):
C12H12N2
CAS号:
分子量:
184.24
Beilstein:
128995
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

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质量水平

方案

99%

表单

solid

mp

169-174 °C (lit.)

SMILES字符串

Cc1ccnc(c1)-c2cc(C)ccn2

InChI

1S/C12H12N2/c1-9-3-5-13-11(7-9)12-8-10(2)4-6-14-12/h3-8H,1-2H3

InChI key

NBPGPQJFYXNFKN-UHFFFAOYSA-N

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应用

4,4′-二甲基-2,2′-联吡啶被用于合成一系列 o-邻菲罗啉取代的钌 (II) 配合物 [1]。它也被用作合成蓝色发光分子的起始材料,发射波长为 450 nm,量子产率为 43% [2]

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

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    Byeong Hyo Kim et al.
    Talanta, 62(3), 595-602 (2008-10-31)
    A series of o-phenanthroline-substituted ruthenium(II) complexes containing 2,2'-dipyridyl, 2-(2-pyridyl)benzimidazole, 2-(2-pyridyl)-N-methylbenzimidazole, 4-carboxymethyl-4'-methyl-2,2'-dipyridyl, and/or 4,4'-dimethyl-2,2'-dipyridyl ligands were synthesized and examined as potent electrochemiluminescent (ECL) materials. The characteristics of these complexes, regarding their electrochemical redox potentials and relative ECL intensities for tripropylamine were
    Journal of Materials Chemistry, 16, 4468-4468 (2006)
    Ricardo Alvarez et al.
    Dalton transactions (Cambridge, England : 2003), 49(28), 9632-9640 (2020-07-03)
    The Nano-Crystallization method has been extensively tested for the growth of single crystals of cationic coordination compounds, which are soluble in water. All three studied, diverse metal complexes could be crystallized with the help of pipetting robots commonly used for
    Maxime Mourer et al.
    Bioorganic & medicinal chemistry, 20(6), 2035-2041 (2012-03-01)
    Various polycharged calix[4]arenes were assayed as anti-mycobacterial agents against Mycobacterium tuberculosis, H(37)Rv strain. The sulfonate, carboxylate and phosphonate anionic species displayed no activity. Cationic derivatives integrating four aminoethyl groups at the upper rim and two 6,6'-dimethyl-2,2'-bipyridyl- or 4,4'-dimethyl-2,2'-bithiazolyl subunits at
    Yang-Hui Luo et al.
    Dalton transactions (Cambridge, England : 2003), 43(44), 16937-16942 (2014-10-11)
    A new iron(II) complex based on the 4,4'-dimethyl-2,2'-bipyridine ligand [Fe(4,4'-dmbpy)3(ClO4)(SCN)·3H2O (1·3H2O)] has been prepared and characterized. Structural studies and Hirshfeld surface analysis for complex 1·3H2O at three different temperatures (300, 240 and 130 K) are described. The UV-vis absorption spectrum

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