所有图片(3)
别名:
(-)-氯甲酸薄荷酯
经验公式（希尔记法）:
C11H19ClO2
CAS号:
分子量:
218.72
Beilstein:
2414686
MDL编号:
UNSPSC代码:
12352101
PubChem化学物质编号:
NACRES:
NA.22
推荐产品
蒸汽压
0.01 psi ( 20 °C)
形式
liquid
旋光性
[α]20/D −83°, c = 1 in chloroform
光学纯度
ee: 99% (GLC)
折射率
n20/D 1.458 (lit.)
bp
108-109 °C/11 mmHg (lit.)
密度
1.02 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
CC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(Cl)=O
InChI
1S/C11H19ClO2/c1-7(2)9-5-4-8(3)6-10(9)14-11(12)13/h7-10H,4-6H2,1-3H3/t8-,9+,10-/m1/s1
InChI key
KIUPCUCGVCGPPA-KXUCPTDWSA-N
应用
1 R ）-(-)-薄荷基氯甲酸酯可用于制备 1- O -薄荷氧羰基 肌醇 -肌醇。
易于形成氯亚氨重碳酸盐，可在温和条件下不对称氯化硅基烯醇醚并且产量高。
用于通过 GC、HPLC 或结晶作用来拆分醇类和胺类的手性衍生试剂。
警示用语：
Danger
危险声明
危险分类
Acute Tox. 3 Inhalation - Skin Corr. 1B
WGK
WGK 3
闪点(°F)
158.0 °F
闪点(°C)
70 °C
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
F Li et al.
Journal of chromatography, 622(2), 187-195 (1993-12-22)
A simple and sensitive high-performance liquid chromatographic (HPLC) method using chiral derivatization was developed to screen and determine the enantiomers of moprolol and their metabolites in human urine. The recovery of (+)- and (-)-moprolol from urine was 70.8-81.1% at different
R O Hughes et al.
Journal of analytical toxicology, 15(5), 256-259 (1991-09-01)
A gas chromatography/mass spectrometry assay was developed for the detection of amphetamine and methamphetamine in urine. These drugs were detected as carbamate derivatives following reaction with (-)-menthyl chloroformate. Selected ion monitoring of the 226, 182, and 227 dalton ions for
Saumen Hajra et al.
The Journal of organic chemistry, 72(13), 4872-4876 (2007-06-05)
New chiral N-chloroimidodicarbonates, which function as efficient chiral chlorinating agents, were designed and synthesized. Among these, C(2)-symmetric (1R,2S,5R)-(-)-menthyl-N-chloroimidodicarbonate 2a provided moderate to good enantioselectivity (up to 40%) for the chlorination of silyl enol ethers to afford alpha-chloroketones only in the
Journal of the Chemical Society. Chemical Communications, 470-470 (1987)
K H Kim et al.
Archives of pharmacal research, 22(6), 608-613 (2000-01-01)
Optimum conditions of chiral derivatization reaction of beta-blockers acebutolol, arotinolol, beta-xolol, bisoprolol, celiprolol, metoprolol and pindolol) with (-)-menthyl chloroformate were investigated for the resolution by HPLC. With more than 30 times molar excess of (-)-menthyl chloroformate chiral derivatization reactions were
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