等级
technical grade
质量水平
形式
liquid
反应适用性
core: cobalt
reagent type: catalyst
bp
139-140 °C/710 mmHg (lit.)
储存温度
2-8°C
SMILES字符串
[Co].[C-]#[O+].[C-]#[O+].[CH]1[CH][CH][CH][CH]1
InChI
1S/C5H5.2CO.Co/c1-2-4-5-3-1;2*1-2;/h1-5H;;;
InChI key
HUSLGLMTBHLWKG-UHFFFAOYSA-N
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应用
炔烃环三聚反应的催化剂。
调节丙二烯二炔经 [2+2+2]-环化反应转化为三环体系的过程。
警示用语:
Danger
危险分类
Acute Tox. 2 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Carc. 2 - Flam. Liq. 3 - Muta. 2 - Repr. 2 - Resp. Sens. 1 - Skin Sens. 1
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Tetrahedron, 62, 10582-10582 (2006)
Room Temperature CpCo-Mediated Cyclization of alpha,delta,omega-Enediynes to Rearranging Strained Tricylic Dienes. Some Observations of Kinetic versus Thermodynamic Control.
The Journal of organic chemistry, 61(14), 4798-4800 (1996-07-12)
Dalton transactions (Cambridge, England : 2003), 49(46), 16821-16829 (2020-11-13)
The reduction of copper(ii) octafluoro- {CuII(F8Pc)} and hexadecafluorophthalocyanines {CuII(F16Pc)} by NaCpCo(CO)2 in the presence of cryptand[2.2.2] yields new crystalline {cryptand(Na+)}[CuII(F8Pc)˙3-]-·2C6H4Cl2 (1) and {cryptand(Na+)}2[CuII(F16Pc)4-]2-·C6H14 (2) salts. Together with two previously characterized salts of CuII(FxPc) (x = 8 and 16), this allows
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