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表单
solid
反应适用性
reagent type: reductant
折射率
n20/D 1.632 (lit.)
沸点
163-165 °C/0.3 mmHg (lit.)
mp
28 °C (lit.)
密度
1.374 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
c1ccc(cc1)[SnH](c2ccccc2)c3ccccc3
InChI
1S/3C6H5.Sn.H/c3*1-2-4-6-5-3-1;;/h3*1-5H;;
InChI key
NFHRNKANAAGQOH-UHFFFAOYSA-N
应用
氢化三苯基锡可作为还原剂用于：
它也可以在9-硼二环[3.3.1]壬烷（9-BBN）作为引发剂的存在下用作自由基还原反应中的自由基前体。
- 在催化量的AIBN存在下的还原性去硒烯化反应。。
- 烯烃的自由基氢锡化。
- α，β-不饱和酮和酯的还原。
它也可以在9-硼二环[3.3.1]壬烷（9-BBN）作为引发剂的存在下用作自由基还原反应中的自由基前体。
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Lingbin Sun et al.
Aquatic toxicology (Amsterdam, Netherlands), 104(3-4), 263-269 (2011-06-07)
Both triphenyltin (TPT) and tributyltin (TBT) have been used as ingredients of antifouling biocides. However, far fewer studies addressing the reproductive toxicity of TPT on fishes are available than for TBT. The present study was conducted to investigate the effects
Jinshao Ye et al.
Bioresource technology, 129, 236-241 (2012-12-19)
Triphenyltin (TPT) is an endocrine disruptor highly toxic to non-target organisms, and has contaminated the environment worldwide. To accelerate TPT elimination, the study on the behavior and mechanism of TPT biosorption and biodegradation by Brevibacillus brevis was conducted. The results
Free radical hydrostannylation of unactivated alkenes with chiral trialkylstannanes
Kavanagh Y, et al.
Organometallics, 30(16), 4387-4392 (2011)
Ítalo Braga Castro et al.
Environmental toxicology and chemistry, 31(5), 947-954 (2012-03-14)
The imposex incidence was appraised in South American gastropods, considering the scenario before and after the global ban of tributyltin (TBT). A statistically significant reduction in imposex indexes was observed in Stramonita haemastoma collected in 2006 and 2010 from areas
Sartaj Tabassum et al.
Metallomics : integrated biometal science, 4(2), 205-217 (2011-12-21)
The novel organotin complex 1-{(2-hydroxyethyl)amino}-2-amino-1,2-dideoxy-D-glucose triphenyltin(iv) (GATPT) was synthesized by the reaction of N-glycoside ligand and triphenyltin(iv) chloride. GATPT was characterized by elemental analyses, polarimetry, IR, CD, UV and multinuclear ((1)H, (13)C, (119)Sn) 1D and 2D NMR. The interaction of
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