蒸汽密度
>1 (vs air)
质量水平
检测方案
99%
形式
liquid
折射率
n20/D 1.417 (lit.)
bp
99-100 °C (lit.)
密度
0.758 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
CC#C[Si](C)(C)C
InChI
1S/C6H12Si/c1-5-6-7(2,3)4/h1-4H3
InChI key
DCGLONGLPGISNX-UHFFFAOYSA-N
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应用
1-（三甲基甲硅烷基）丙炔被用于通过钯催化的碳环化反应合成高度取代的茚，以及通过铑催化的与2-溴苯基硼酸的反应合成茚酮。
警示用语：
Danger
危险声明
危险分类
Flam. Liq. 2
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Journal of the American Chemical Society, 105, 7473-7473 (1983)
Tetrahedron Letters, 33, 5969-5969 (1992)
Yasuyuki Harada et al.
Journal of the American Chemical Society, 129(17), 5766-5771 (2007-04-10)
The Rh-catalyzed reaction of alkynes with 2-bromophenylboronic acids involves carbonylative cyclization to give indenones. The key steps in the reaction involve the addition of an arylrhodium(I) species to an alkyne and the oxidative addition of C-Br bonds on the adjacent
Journal of Polymer Science Part A: Polymer Chemistry, 25, 1353-1353 (1987)
Daohua Zhang et al.
The Journal of organic chemistry, 72(1), 251-262 (2006-12-30)
The synthesis of highly substituted indenes has been achieved by three different transition metal-mediated methods. The first method involves the palladium-catalyzed carboannulation of internal alkynes. The second method utilizes a two-step approach, which involves first the palladium/copper-catalyzed cross-coupling of terminal
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