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蒸汽压
253 mmHg ( 37.7 °C)
质量水平
方案
97%
表单
liquid
杂质
<2% 1-bromobutane
折射率
n20/D 1.399 (lit.)
沸点
71-72 °C (lit.)
mp
−132 °C (lit.)
密度
0.715 g/mL at 25 °C (lit.)
SMILES字符串
CCCCC#C
InChI
1S/C6H10/c1-3-5-6-4-2/h1H,4-6H2,2H3
InChI key
CGHIBGNXEGJPQZ-UHFFFAOYSA-N
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一般描述
1-己炔与噻吩阳离子自由基四氟硼酸盐反应生成 反式 -1,2- 双 (5-噻蒽)烯烃四氟硼酸盐 。
应用
1-己炔通过氢锆和关环复分解 (RCM) 被用于合成三环异吲哚酮骨架 。
警示用语:
Danger
危险分类
Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
-4.0 °F - closed cup
闪点(°C)
-20 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Medicinal chemistry (Shariqah (United Arab Emirates)), 15(4), 400-408 (2018-10-27)
The trypanosomatids, such as the protozoan Leishmania spp., have a demand by ergosterol, which is not present in the membrane from mammal cells. The suppression of the synthesis of ergosterol would be a new target of compounds with leishmanicidal activity
The Journal of arthroplasty, 33(8), 2666-2670 (2018-05-23)
Wear resistance of ultrahigh molecular weight polyethylene (UHMWPE) is improved via ionizing radiation crosslinking and subsequent high temperature melting for improved toughness. Our group has previously reported that crosslinking can also be achieved chemically using organic peroxides. However, volatile peroxide
Beilstein journal of organic chemistry, 8, 1091-1097 (2012-09-29)
Hydrozirconation of 1-hexyne, the addition to in situ prepared N-acyliminium species, and ring-closing metathesis (RCM) were key steps in the preparation of a tricyclic isoindolinone scaffold. An unusual alkene isomerization process during the RCM was identified and studied in some
Molecules (Basel, Switzerland), 24(1) (2019-01-10)
Herein, we investigated the effect of ring planarity by fully characterizing four pyridine-based o-carboranyl compounds. o-Carborane was introduced to the C4 position of the pyridine rings of 2-phenylpyridine and 2-(benzo[b]thiophen-2-yl)pyridine (CB1 and CB2, respectively), and the compounds were subsequently borylated
Journal of chromatography. A, 1523, 316-320 (2017-06-26)
Silver ion or argentation chromatography utilizes stationary phases containing silver ions for the separation of unsaturated compounds. In this study, a mixed-ligand silver-based ionic liquid (IL) was evaluated for the first time as a gas chromatographic (GC) stationary phase for
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