244341
2-丁炔-1-醇
98%
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线性分子式:
CH3C≡CCH2OH
化学文摘社编号:
分子量:
70.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-113-4
Beilstein/REAXYS Number:
1733676
MDL number:
产品名称
2-丁炔-1-醇, 98%
InChI key
NEEDEQSZOUAJMU-UHFFFAOYSA-N
InChI
1S/C4H6O/c1-2-3-4-5/h5H,4H2,1H3
SMILES string
CC#CCO
assay
98%
form
liquid
refractive index
n20/D 1.453 (lit.)
bp
142-143 °C (lit.)
mp
−2.2 °C (lit.)
density
0.937 g/mL at 25 °C (lit.)
functional group
hydroxyl
Quality Level
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Application
2-丁炔-1-醇用于合成同偶联产物 {Ru (P (OCH 3 ) 3 ) 2 (CH 3 CN) 3 } 2 {μ-[OCH 2 CCR}] (CF 3 SO 3 ) 4 。
通过环己烷和环己烯与烯丙基侧链的复分解反应合成大环醚。†
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
123.8 °F - closed cup
flash_point_c
51 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
European Journal of Organic Chemistry, 3727-3727 (2007)
Kazuko Matsumoto et al.
Journal of the American Chemical Society, 124(44), 13106-13113 (2002-10-31)
A variety of inter- and intramolecular dehydration was found in the reactions of [[Ru(P(OCH(3))(3))(2)(CH(3)CN)(3)](2)(mu-S(2))](CF(3)SO(3))(4) (1) with hydroxyl substituted alkenes and alkynes. Treatment of 1 with allyl alcohol gave a C(3)S(2) five-membered ring complex, [[Ru(P(OCH(3))(3))(2)(CH(3)CN)(3)](2)[mu-SCH(2)CH(2)CH(OCH(2)CH=CH(2))S]](CF(3)SO(3))(4) (2), via C-S bond formation after
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