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Merck
CN

243159

Sigma-Aldrich

(R)-3-羟基丁酸甲酯

99%

别名:

(-)-(3R)-3-羟基丁酸甲酯, (-)-3-羟基丁酸甲酯, (3R)-羟基丁酸甲酯, (R)-β-羟基丁酸甲酯

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About This Item

线性分子式:
CH3CH(OH)CH2CO2CH3
CAS号:
分子量:
118.13
Beilstein:
6130687
EC 号:
MDL编号:
UNSPSC代码:
12352108
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

99%

旋光性

[α]20/D −19.5°, neat

光学纯度

ee: 98% (GLC)

折射率

n20/D 1.421 (lit.)

沸点

56-58 °C/11 mmHg (lit.)

密度

1.055 g/mL at 20 °C (lit.)

官能团

ester
hydroxyl

储存温度

2-8°C

SMILES字符串

COC(=O)C[C@@H](C)O

InChI

1S/C5H10O3/c1-4(6)3-5(7)8-2/h4,6H,3H2,1-2H3/t4-/m1/s1

InChI key

LDLDJEAVRNAEBW-SCSAIBSYSA-N

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应用

( R )-3-羟基丁酸甲酯可用于 ( R )-(-)-3-羟基丁酸 和聚 ( R )-(-)-3-羟基丁酸酯的制备。
光学活性起始材料

包装

无底玻璃瓶。内含物装在插入的融合锥内。

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

163.4 °F - closed cup

闪点(°C)

73 °C - closed cup

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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分析证书(COA)

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Direct Degradation of the Biopolymer Poly [(R)-3-Hydroxybutyric Acid] to (R)-3-Hydroxybutanoic Acid and its Methyl Ester.
Seebach D, et al.
Organic Syntheses, 39-39 (1992)
Synthesis of biodegradable polyesters by polycondensation of methyl (R)-3-hydroxybutyrate and methyl (R)-3-hydroxy-valerate.
Kobayashi T, et al.
Makromol. Chem., Rapid Commun., 14(12), 785-790 (1993)
Diya Alsafadi et al.
New biotechnology, 34, 47-53 (2016-05-26)
Olive mill wastewater (OMW), a highly polluting waste from the olive oil industry, was utilized as sole carbon source for the production of polyhydroxyalkanoate (PHA) by extremely halophilic Haloferax Mediterranei (H. mediterranei) in a one stage cultivation step. H. mediterranei
Xiao-Hong Chen et al.
PloS one, 9(4), e94543-e94543 (2014-04-18)
A novel carbonyl reductase (AcCR) catalyzing the asymmetric reduction of ketones to enantiopure alcohols with anti-Prelog stereoselectivity was found in Acetobacter sp. CCTCC M209061 and enriched 27.5-fold with an overall yield of 0.4% by purification. The enzyme showed a homotetrameric

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