推荐产品
质量水平
方案
98%
折射率
n20/D 1.503 (lit.)
沸点
179-180 °C (lit.)
密度
1.808 g/mL at 25 °C (lit.)
官能团
ester
iodo
储存温度
2-8°C
SMILES字符串
CCOC(=O)CI
InChI
1S/C4H7IO2/c1-2-7-4(6)3-5/h2-3H2,1H3
InChI key
MFFXVVHUKRKXCI-UHFFFAOYSA-N
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应用
Ethyl iodoacetate was used in the synthesis of trans-2,3-disubstituted indolines by reacting with 1-azido-2-allylbenzene derivatives via a diastereoselective radical cascade.
警示用语：
Danger
危险声明
危险分类
Acute Tox. 2 Oral - Eye Dam. 1 - Skin Corr. 1B
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
闪点(°F)
170.6 °F - closed cup
闪点(°C)
77 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
François Brucelle et al.
The Journal of organic chemistry, 78(12), 6245-6252 (2013-06-01)
The preparation of trans-2,3-disubstituted indolines from 1-azido-2-allylbenzene derivatives via a diastereoselective radical cascade using ethyl iodoacetate and triethylborane is described. Further lactamization afforded substituted benzopyrrolizidinones with excellent diastereomeric ratios. The radical cascade/lactamization sequence was efficiently applied to the synthesis of
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