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Merck
CN

242306

Sigma-Aldrich

氯甲酸烯丙酯

97%, for peptide synthesis

别名:

2-Propen-1-yl chloroformate, Allyloxycarbonyl chloride

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About This Item

线性分子式:
ClCOOCH2CH=CH2
CAS号:
分子量:
120.53
Beilstein:
773915
EC 号:
MDL编号:
UNSPSC代码:
12190000
PubChem化学物质编号:
NACRES:
NA.22

产品名称

氯甲酸烯丙酯, 97%

蒸汽压

3.67 psi ( 20 °C)

质量水平

方案

97%

表单

liquid

折射率

n20/D 1.422 (lit.)

沸点

~27 °C/11 mmHg (lit.)

密度

1.134 g/mL at 20 °C (lit.)

应用

peptide synthesis

储存温度

−20°C

SMILES字符串

ClC(=O)OCC=C

InChI

1S/C4H5ClO2/c1-2-3-7-4(5)6/h2H,1,3H2

InChI key

CAEWJEXPFKNBQL-UHFFFAOYSA-N

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一般描述

氯甲酸烯丙酯是一种有机化合物,用于合成各种化合物,如烯丙基氨基甲酸酯和烯丙基碳酸酯。此外,它可用于制备α-烯丙基羰基和α, β-不饱和羰基。

应用

氯甲酸烯丙酯可用于合成:
  • 组蛋白及其类似物。
  • 由环硫酯(d,l-高半胱氨酸 硫内脂盐酸盐)生成Alloc-TL单体 (N-(烯丙氧基)羰基高半胱氨酸硫代内酯) 。

警示用语:

Danger

危险分类

Acute Tox. 1 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 3 - Skin Corr. 1B

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

87.8 °F - closed cup

闪点(°C)

31 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Allyl Chloroformate
Herrinton PM
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2001)
Thiolactone-based polymers for formaldehyde scavenging coatings
Resetco C, et al.
European Polymer Journal, 82, 166-174 (2016)
Palladium-catalyzed synthesis of substituted cycloheptane-1,4-diones by an asymmetric ring-expanding allylation (AREA).
Sabrina R Schulz et al.
Angewandte Chemie (International ed. in English), 46(21), 3966-3970 (2007-04-20)
Carlos E Cuevas-Suárez et al.
Journal of the mechanical behavior of biomedical materials, 87, 148-154 (2018-08-03)
Over the past years, significant effort has been dedicated to synthesizing low-shrinking formulations, however, development of dental composites with low volumetric shrinkage continues to be challenging. The purpose of this study was to synthesize a bisphenol allylic derivate (BPhADAC) and
William R Cantrell et al.
Nucleosides, nucleotides & nucleic acids, 27(8), 901-913 (2008-08-13)
Degradation of clofarabine (3) in 0.9% saline solution at 100 degrees C afforded three degradation products which were determined to be formamidopyrimidines 4-6. Compounds 4 and 5 were assigned as C(1') anomers on the basis of one-dimensional and two-dimensional NMR

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