242306
氯甲酸烯丙酯
97%, for peptide synthesis
别名:
2-Propen-1-yl chloroformate, Allyloxycarbonyl chloride
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关于此项目
线性分子式:
ClCOOCH2CH=CH2
化学文摘社编号:
分子量:
120.53
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12190000
EC Number:
220-916-6
MDL number:
Beilstein/REAXYS Number:
773915
产品名称
氯甲酸烯丙酯, 97%
InChI key
CAEWJEXPFKNBQL-UHFFFAOYSA-N
InChI
1S/C4H5ClO2/c1-2-3-7-4(5)6/h2H,1,3H2
SMILES string
ClC(=O)OCC=C
vapor pressure
3.67 psi ( 20 °C)
assay
97%
form
liquid
refractive index
n20/D 1.422 (lit.)
bp
~27 °C/11 mmHg (lit.)
density
1.134 g/mL at 20 °C (lit.)
application(s)
peptide synthesis
storage temp.
−20°C
Quality Level
General description
氯甲酸烯丙酯是一种有机化合物，用于合成各种化合物，如烯丙基氨基甲酸酯和烯丙基碳酸酯。此外，它可用于制备α-烯丙基羰基和α, β-不饱和羰基。
Application
氯甲酸烯丙酯可用于合成：
- 组蛋白及其类似物。
- 由环硫酯(d,l-高半胱氨酸 硫内脂盐酸盐)生成Alloc-TL单体 (N-(烯丙氧基)羰基高半胱氨酸硫代内酯) 。
Disclaimer
Supply conditions do not apply to the regions and states of Brazil: North, Northeast, Mato Grosso do Sul, Mato Grosso, and Rio Grande do Sul.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 3 - Skin Corr. 1B
存储类别
3 - Flammable liquids
flash_point_f
87.8 °F - closed cup
flash_point_c
31 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Allyl Chloroformate
Herrinton PM
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2001)
Total chemical synthesis of histones and their analogs, assisted by native chemical ligation and palladium complexes
Maity SK, et al.
Nature Protocols, 11(12), 2293-2322 (2017)
Palladium-catalyzed synthesis of substituted cycloheptane-1,4-diones by an asymmetric ring-expanding allylation (AREA).
Sabrina R Schulz et al.
Angewandte Chemie (International ed. in English), 46(21), 3966-3970 (2007-04-20)
Carlos E Cuevas-Suárez et al.
Journal of the mechanical behavior of biomedical materials, 87, 148-154 (2018-08-03)
Over the past years, significant effort has been dedicated to synthesizing low-shrinking formulations, however, development of dental composites with low volumetric shrinkage continues to be challenging. The purpose of this study was to synthesize a bisphenol allylic derivate (BPhADAC) and
Thiolactone-based polymers for formaldehyde scavenging coatings
Resetco C, et al.
European Polymer Journal, 82, 166-174 (2016)
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