所有图片(2)
About This Item
线性分子式:
LiAlH[OC(CH3)3]3
CAS号:
分子量:
254.27
Beilstein:
5796791
MDL编号:
UNSPSC代码:
12352000
PubChem化学物质编号:
NACRES:
NA.22
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表单
liquid
质量水平
反应适用性
reagent type: reductant
浓度
1.0 M in THF
密度
0.904 g/mL at 25 °C
SMILES字符串
[Li+].CC(C)(C)O[AlH-](OC(C)(C)C)OC(C)(C)C
InChI
1S/3C4H9O.Al.Li.H/c3*1-4(2,3)5;;;/h3*1-3H3;;;/q3*-1;+2;+1;
InChI key
BYBIDFZFKATBFH-UHFFFAOYSA-N
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一般描述
三叔丁 氧基氢化铝锂是一种温和的还原剂 ，主要用于酮的选择性还原。
应用
- 还原剂
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
靶器官
Respiratory system
补充剂危害
储存分类代码
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 1
闪点(°F)
1.4 °F - closed cup
闪点(°C)
-17 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
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Organic Syntheses, 58-67 (2007)
The use of 4, 4-disubstituted nopinones for natural-product synthesis. Synthesis of elemanoid sesquiterpenes.
Kato M, et al.
The Journal of Organic Chemistry, 56(25), 7071-7076 (1991)
Stereoselectivity of lithium tri-tert-butoxyaluminum hydride.
Ashby EC, et al.
The Journal of Organic Chemistry, 36(1), 197-199 (1971)
Synthesis of an enantiomerically pure intermediate containing the CD substructure of taxol.
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M Gobbini et al.
Bioorganic & medicinal chemistry, 6(10), 1889-1894 (1998-12-05)
The four stereoisomers of the 2-hydroxy derivatives of digitoxigenin and 3-epidigitoxigenin have been synthesized, their structures established by NMR, and their binding affinity for the digitalis receptor on Na+, K(+)-ATPase evaluated. These derivatives showed lower affinities than the parent compounds.
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