241806
(R)-(-)-甘油醇缩丙酮
98%
别名:
2,3-异亚丙基-sn-甘油, L-α,β-异亚丙基甘油, L-2,3-O-异亚丙基-sn-甘油
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关于此项目
经验公式（希尔记法）:
C6H12O3
化学文摘社编号:
分子量:
132.16
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
80117
Assay:
98%
Form:
liquid
Quality Level
InChI
1S/C6H12O3/c1-6(2)8-4-5(3-7)9-6/h5,7H,3-4H2,1-2H3/t5-/m1/s1
SMILES string
CC1(C)OC[C@@H](CO)O1
InChI key
RNVYQYLELCKWAN-RXMQYKEDSA-N
assay
98%
form
liquid
optical activity
[α]20/D −13.7°, neat
optical purity
ee: 98% (GLC)
refractive index
n20/D 1.434 (lit.)
bp
72-73 °C/8 mmHg (lit.)
density
1.062 g/mL at 25 °C (lit.)
functional group
ether, hydroxyl, ketal
storage temp.
2-8°C
Application
(R)-(-)-2,2-二甲基-1,3-二氧戊环-4-甲醇可用于制备：
- ( R )-2,2-二甲基-4-苯氧基甲基-1,3-二氧杂环戊烷
- （( S )-（2,2-二甲基-1,3-二氧杂环戊烷-4-基）甲基 4-甲基苯磺酸酯）-1,3-二氧杂环戊烷
- ( S )-甘油醛缩丙酮
- 四氧杂螺十一烷、甘油二酯、磷酸甘油酯和螺吡喃。
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
174.2 °F - closed cup
flash_point_c
79 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
法规信息
新产品
此项目有
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Ji N, et al.
Journal of the American Chemical Society, 128(46), 14825-14825 (2006)
A cytosine analogue containing a conformationally flexible acyclic linker for triplex formation at sites with contiguous GC base pairs.
Xiang G and McLaughlin LW.
Tetrahedron, 54(3), 375-392 (1998)
2- and 8- functionalized 1,4,7,10-tetraoxaspiro[5.5]undecanes.: II. Synthesis of (+)-E,E and (?)-Z,E structures from chiral isopropylideneglycerols.
Marielle Lemaire
Tetrahedron Asymmetry, 4. 9, 2101-2108 (1993)
European Journal of Organic Chemistry, 4805-4805 (2006)
S-Aryl-L-cysteine S,S-dioxides: design, synthesis, and evaluation of a new class of inhibitors of kynureninase
Rajesh K. Dua,
Journal of the American Chemical Society, 115, 4, 1264-1270 (1993)
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