所有图片(2)
About This Item
线性分子式:
[(CH3)2CH]3SiCl
CAS号:
分子量:
192.80
Beilstein:
1737446
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
蒸汽压
1.16 mmHg ( 20 °C)
质量水平
检测方案
97%
形式
liquid
折射率
n20/D 1.452 (lit.)
bp
198 °C/739 mmHg (lit.)
密度
0.901 g/mL at 25 °C (lit.)
SMILES字符串
CC(C)[Si](Cl)(C(C)C)C(C)C
InChI
1S/C9H21ClSi/c1-7(2)11(10,8(3)4)9(5)6/h7-9H,1-6H3
InChI key
KQIADDMXRMTWHZ-UHFFFAOYSA-N
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应用
TIPS 取代炔烃可用于由铬卡宾络合物制备硅基乙烯基烯酮。
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Greene, T.W. Wuts, P.G.M.
Protective Groups in Organic Synthesis (1991)
William H Moser et al.
The Journal of organic chemistry, 71(17), 6542-6546 (2006-08-12)
Stable silyl vinylketenes were prepared via the thermal reaction of Fischer carbene complexes with triisopropylsilyl- or tert-butyldimethylsilyl-substituted alkynes. The ability of these silyl vinylketenes to participate with carbenoid reagents in [4 + 1] annulation reactions was investigated. The best results
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