241458
六羰基铬
98%
别名:
六羰基铬
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线性分子式:
Cr(CO)6
化学文摘社编号:
分子量:
220.06
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
235-852-4
MDL number:
产品名称
六羰基铬, 98%
InChI key
KOTQLLUQLXWWDK-UHFFFAOYSA-N
InChI
1S/6CO.Cr/c6*1-2;
SMILES string
[Cr].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
vapor density
7.6 (vs air)
vapor pressure
1 mmHg ( 36 °C)
assay
98%
reaction suitability
core: chromium
reagent type: catalyst
mp
>150 °C (dec.) (lit.)
density
1.77 g/mL at 25 °C (lit.)
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Application
异戊烯基碳烯络合物的前体，该络合物可促进炔基苯甲醛的网状 [5+5] 环加成，生成菲。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Suneetha Menon et al.
Tetrahedron, 63(36), 8788-8793 (2008-09-05)
The reaction of prenylated carbene complexes and 2-alkynylbenzoyl derivatives has been investigated. Phenanthrene derivatives are produced if iodine is added prior to product isolation. Under these conditions alkyl migration reactions occur to form the observed products. The product yields are
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