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Merck
CN

239615

Sigma-Aldrich

4-皮考啉

99%

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别名:
4-甲基吡啶
经验公式(希尔记法):
C6H7N
CAS号:
分子量:
93.13
Beilstein:
104586
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽密度

3.2 (vs air)

质量水平

蒸汽压

4 mmHg ( 20 °C)

检测方案

99%

自燃温度

1000 °F

折射率

n20/D 1.504 (lit.)

bp

145 °C (lit.)

mp

2.4 °C (lit.)

溶解性

alcohol: soluble(lit.)
diethyl ether: soluble(lit.)
water: soluble(lit.)

密度

0.957 g/mL at 25 °C (lit.)

SMILES字符串

Cc1ccncc1

InChI

1S/C6H7N/c1-6-2-4-7-5-3-6/h2-5H,1H3

InChI key

FKNQCJSGGFJEIZ-UHFFFAOYSA-N

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一般描述

The reaction of 4-methylpyridine with naphthyl tosylate, that occurred on the methyl group, was studied.

应用

4-Methylpyridine was used in the synthesis of mercury (II) metallacycle.

象形图

FlameSkull and crossbones

警示用语:

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 1

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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Fenglin Dai et al.
Chemical communications (Cambridge, England), 49(41), 4634-4636 (2013-04-12)
We have discovered that phenyl tosylates can be used to arylate pyridines at the C3-position using a Pd(OAc)2-1,10-phenanthroline catalyst system. We also discovered that the reaction of 4-methylpyridine with naphthyl tosylates occurred on the methyl group instead of at the
Bhaskar Nath et al.
Dalton transactions (Cambridge, England : 2003), 41(23), 7115-7126 (2012-05-09)
A series of linear coordination polymers, metallacycles of cadmium(II) and mercury(II) of flexible carboxylic acid ligands, RCH{3-CH(3)-,5-CH(3)-,6-(-OCH(2)CO(2)H)C(6)H(2)}(2), (when R = C(6)H(5), (H(2)L(1)); 2-NO(2)C(6)H(4)- (H(2)L(2)) and 3-NO(2)C(6)H(4)- (H(2)L(3))) are synthesized and characterized. [CdL(1) (py)(3)](n)·3nH(2)O (py = pyridine) is a linear coordination
Stéphanie Romand et al.
European journal of pharmaceutical sciences : official journal of the European Federation for Pharmaceutical Sciences, 63, 14-21 (2014-07-06)
A capillary isoelectric focusing (cIEF) method was developed for the determination of the ionization constants (pKa) of small molecules. Two approaches used to decrease the electroosmotic flow (EOF) were compared: (i) a hydroxypropylcellulose (HPC) coated capillary in aqueous medium and

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