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质量水平
方案
98%
表单
liquid
包含
copper as stabilizer
折射率
n20/D 1.554 (lit.)
沸点
102-103 °C (lit.)
溶解性
alcohol: miscible(lit.)
chloroform: miscible(lit.)
diethyl ether: miscible(lit.)
water: insoluble (practically)(lit.)
密度
1.837 g/mL at 25 °C (lit.)
官能团
alkyl halide
iodo
储存温度
2-8°C
SMILES字符串
ICC=C
InChI
1S/C3H5I/c1-2-3-4/h2H,1,3H2
InChI key
HFEHLDPGIKPNKL-UHFFFAOYSA-N
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一般描述
研究了在 270～480℃ 温度范围内，烯丙基碘化物与 MoO3, Bi2O3和 Bi、Co、Mg 的钼酸盐的相互作用。
应用
使用的烯丙基碘为：
- 气相色谱法研究烯丙基化合物在单脉冲激波管中的复合
- 在环丙烯的顺式-双烯丙基化反应中与烯丙基倍半碘化钠配合使用的试剂
警示用语：
Danger
危险声明
危险分类
Acute Tox. 2 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
60.8 °F - closed cup
闪点(°C)
16 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Xin Ma et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(25), 6355-6361 (2019-02-28)
Unexpectedly, the 5-dehydroquinoline radical cation was formed in the gas phase from the 5-iodo-8-nitroquinolinium cation upon ion-trap collision-activated dissociation. This reaction involves the cleavage of a nitro group to generate an intermediate monoradical, namely, the 8-dehydro-5-iodoquinolinium cation, followed by rearrangement
Tsunehisa Hirashita et al.
Organic & biomolecular chemistry, 5(13), 2154-2158 (2007-06-22)
The successive double allylation of cyclopropenes with allylindium sesquiiodide and allyl iodide proceeded with a cis-addition mode in the presence of other organometallics (e.g. Grignard reagent, cuprate, Et(2)Zn and Et(3)Al), giving the corresponding cis-diallylcyclopropanes in high yields.
Aleksandr Fridlyand et al.
The journal of physical chemistry. A, 117(23), 4762-4776 (2013-05-18)
The recombination and disproportionation of allyl radicals has been studied in a single pulse shock tube with gas chromatographic measurements at 1-10 bar, 650-1300 K, and 1.4-2 ms reaction times. 1,5-Hexadiene and allyl iodide were used as precursors. Simulation of
Interaction of allyl iodide with molybdate catalysts for the selective oxidation of hydrocarbons.
Grzybowska B, et al.
J. Catal., 49(2), 150-163 (1977)
Michael Lesslie et al.
European journal of mass spectrometry (Chichester, England), 21(3), 589-597 (2015-08-27)
Radical migration, both intramolecular and intermolecular, from the tyrosine phenoxyl radical Tyr(O(∙)) to the cysteine radical Cys(S(∙)) in model peptide systems was observed in the gas phase. Ion-molecule reactions (IMRs) between the radical cation of homotyrosine and propyl thiol resulted
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