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质量水平
方案
≥98%
表单
liquid
包含
copper as stabilizer
折射率
n20/D 1.492 (lit.)
沸点
179-180 °C (lit.)
密度
1.437 g/mL at 25 °C (lit.)
官能团
alkyl halide
iodo
SMILES字符串
CCCCCCI
InChI
1S/C6H13I/c1-2-3-4-5-6-7/h2-6H2,1H3
InChI key
ANOOTOPTCJRUPK-UHFFFAOYSA-N
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一般描述
1-碘代己烷与 9-辛基-9-硼杂双环发生钯催化的交叉偶联反应 [3.3.l] 壬烷给十四烷。用程序升温脱附和 X 射线光电子能谱研究了 1-碘代己烷在 Ni (100) 单晶表面上的热反应。
警示用语:
Warning
危险声明
危险分类
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
141.8 °F - closed cup
闪点(°C)
61 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Thermal Reactions of Alkyl Iodides on Ni (100) Single Crystal Surfaces.
Tjandra S and Zaera F.
Journal of the American Chemical Society, 117(38), 9749-9755 (1995)
Palladium-catalyzed carbonylative cross-coupling reaction of iodoalkanes with 9-alkyl-9-BBN derivatives. A direct and selective synthesis of ketones.
Ishiyama T and Miyaura N.
Tetrahedron Letters, 32(47), 6923-6926 (1991)
Martha Kafetzi et al.
Polymers, 13(3) (2021-01-27)
In this work, the synthesis and the aqueous solution self-assembly behavior of novel partially hydrophobically modified poly(2-(dimethylamino) ethyl methacrylate)-b-poly(oligo(ethylelene glycol) methyl ether methacrylatetabel) pH and temperature responsive random diblock copolymers (P(DMAEMA-co-Q6/12DMAEMA)-b-POEGMA), are reported. The chemical modifications were accomplished via quaternization
Barbara Nozière et al.
Angewandte Chemie (International ed. in English), 58(39), 13976-13982 (2019-07-31)
The autoxidation of organic peroxy radicals (RO2 ) into hydroperoxy-alkyl radicals (QOOH), then hydroperoxy-peroxy radicals (HOOQO2 ) is now considered to be important in the Earth's atmosphere. To avoid mechanistic uncertainties these reactions are best studied by monitoring the radicals.
Alexa Schmitz et al.
ChemistryOpen, 10(2), 153-163 (2020-12-24)
S-alkyltetrahydrothiophenium, [Cn THT]+ bis(trifluorosulfonyl)imide, [NTf2 ]- room temperature ionic liquids (ILs) and tetraphenylborate, [BPh4 ]- salts with alkyl chain lengths from C4 to C10 have been prepared. The ILs and salts were characterized and their purity verified by 1 H-
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