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质量水平
方案
98%
表单
liquid
包含
copper as stabilizer
折射率
n20/D 1.484 (lit.)
沸点
159-160 °C/15 mmHg (lit.)
mp
−3 °C (lit.)
密度
1.201 g/mL at 25 °C (lit.)
官能团
alkyl halide
iodo
SMILES字符串
CCCCCCCCCCCCI
InChI
1S/C12H25I/c1-2-3-4-5-6-7-8-9-10-11-12-13/h2-12H2,1H3
InChI key
GCDPERPXPREHJF-UHFFFAOYSA-N
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一般描述
已经研究了在LiBr、LiCl和六甲基磷酰胺(HMPA)存在下SmI2介导的1-碘十二烷 和2-辛酮的偶联。
应用
1-碘十二烷已被用于合成:
- 十二烷基石墨
- 烷基官能化的单壁碳纳米管(SWNT)
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
230.0 °F - closed cup
闪点(°C)
110 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Robin E Anderson et al.
Journal of nanoscience and nanotechnology, 7(10), 3436-3440 (2008-03-12)
Single walled carbon nanotubes (SWNTs) may be made soluble in a range of organic solvents without sidewall functionalization via their reduction by Na/Hg amalgam in the presence of dibenzo-18-crown-6. The [Na(dibenzo-18-crown-6)]n[SWNT] complex has been characterized by UV-Visible, Raman, and AFM
Reactions of SmI2 with alkyl halides and ketones: Inner-sphere vs outer-sphere electron transfer in reactions of Sm (II) reductants.
Miller RS, et al.
Journal of the American Chemical Society, 122(32), 7718-7722 (2000)
Minhuan Li et al.
Science advances, 6(27), eaaw8938-eaaw8938 (2020-07-14)
Most systems have more than two stable crystalline states in the phase diagram, which is known as polymorphism. Crystallization in such a system is often under strong influence of competing orderings linked to those crystals. However, how such competition affects
Functionalization of potassium graphite.
Soma Chakraborty et al.
Angewandte Chemie (International ed. in English), 46(24), 4486-4488 (2007-05-05)
Martha Kafetzi et al.
Polymers, 13(3) (2021-01-27)
In this work, the synthesis and the aqueous solution self-assembly behavior of novel partially hydrophobically modified poly(2-(dimethylamino) ethyl methacrylate)-b-poly(oligo(ethylelene glycol) methyl ether methacrylatetabel) pH and temperature responsive random diblock copolymers (P(DMAEMA-co-Q6/12DMAEMA)-b-POEGMA), are reported. The chemical modifications were accomplished via quaternization
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