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质量水平
方案
98%
表单
liquid
包含
copper as stabilizer
折射率
n20/D 1.5441 (lit.)
沸点
80-81 °C/20 mmHg (lit.)
密度
1.624 g/mL at 25 °C (lit.)
官能团
iodo
储存温度
2-8°C
SMILES字符串
IC1CCCCC1
InChI
1S/C6H11I/c7-6-4-2-1-3-5-6/h6H,1-5H2
InChI key
FUCOMWZKWIEKRK-UHFFFAOYSA-N
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一般描述
用速度图成像方法研究了碘环烷基的光解动力学。研究了镍催化碘环己烷与1-辛炔的偶联反应。
应用
在回流条件下，采用碘环烷基对DMF中的芳基甲基醚进行脱甲基反应。
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
158.0 °F - closed cup
闪点(°C)
70 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
D K Zaouris et al.
The Journal of chemical physics, 135(9), 094312-094312 (2011-09-15)
The photodissociation dynamics of iodocyclohexane has been studied using velocity map imaging following excitation at many wavelengths within its A-band (230 ≤ λ ≤ 305 nm). This molecule exists in two conformations (axial and equatorial), and one aim of the
An efficient method for demethylation of aryl methyl ethers.
Zuo L, et al.
Tetrahedron Letters, 49(25), 4054-4056 (2008)
Jun Yi et al.
Angewandte Chemie (International ed. in English), 52(47), 12409-12413 (2013-10-12)
A nicked reaction: The title reaction of terminal alkynes with non-activated secondary alkyl iodides and bromides was accomplished for the first time. This reaction provides a new and practical approach for the synthesis of substituted alkynes (see scheme; cod=cyclo-1,5-octadiene).
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