237906
氯甲酸苯酯
97%
别名:
苯基氯甲酸酯
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关于此项目
线性分子式:
ClCOOC6H5
化学文摘社编号:
分子量:
156.57
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
217-547-8
Beilstein/REAXYS Number:
606778
MDL number:
Assay:
97%
Form:
liquid
InChI key
AHWALFGBDFAJAI-UHFFFAOYSA-N
InChI
1S/C7H5ClO2/c8-7(9)10-6-4-2-1-3-5-6/h1-5H
SMILES string
ClC(=O)Oc1ccccc1
vapor density
1 (vs air)
vapor pressure
1.22 psi ( 20 °C), 1.67 psi ( 55 °C)
assay
97%
form
liquid
Quality Level
bp
74-75 °C/13 mmHg (lit.)
density
1.248 g/mL at 25 °C (lit.)
functional group
chloro, phenoxy
storage temp.
2-8°C
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General description
研究了氯甲酸苯酯在水-乙二醇、阳离子、两性离子、非离子和阴离子胶束溶液中的自发水解动力学，。
Application
氯甲酸苯酯已经用于聚（2-（苯氧羰基氧基）甲基丙烯酸乙酯）和苯基-（4-乙烯基苯基）碳酸的合成。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
156.2 °F - closed cup
flash_point_c
69 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Synthesis and ligand recognition of paracetamol selective polymers: semi-covalent versus non-covalent molecular imprinting.
Rosengren-Holmberg JP, et al.
Organic & Biomolecular Chemistry, 7(15), 3148-3155 (2009)
Amalia Rodríguez et al.
Langmuir : the ACS journal of surfaces and colloids, 20(23), 9945-9952 (2004-11-03)
The spontaneous hydrolysis of phenyl chloroformate was studied in water-ethylene glycol, EG, cationic, zwitterionic, nonionic, and anionic micellar solutions, the surfactants being tetradecyltrimethylammonium bromide, tetradecyl-N,N-dimethyl-3-ammonio-1-propanesulfonate, tricosaoxyethylene glycol ether, and sodium dodecyl sulfate. The dependence of the observed rate constant on
Luis García-Río et al.
Langmuir : the ACS journal of surfaces and colloids, 21(17), 7672-7679 (2005-08-11)
A study was carried out on the solvolysis of substituted phenyl chloroformates in AOT/isooctane/water microemulsions. (AOT is the sodium salt of bis(2-ethyhexyl)sulfosuccinate.) The results obtained have been interpreted by taking into account the distribution of the chloroformates between the continuous
R K Keller et al.
Biochemistry, 20(20), 5831-5836 (1981-09-29)
A sensitive assay is described for quantitating dolichyl phosphate (Dol-P), the polyprenyl phospholipid which participates in N-linked glycosylation. The assay is based on a novel reaction of alkyl phosphates with phenyl chloroformate in which a monosubstituted mixed anhydride of phosphoric
B Boettcher et al.
Analytical biochemistry, 138(2), 449-450 (1984-05-01)
An improved synthesis of L-2- oxothiazolidine -4-carboxylic acid is described. The new procedure, which leads to excellent yields of product, does not require the use of phosgene. The new method is thus less hazardous than the original one, and is
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