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蒸汽密度
2.6 (vs air)
质量水平
蒸汽压
12.5 mmHg ( 20 °C)
方案
99%
表单
liquid
旋光性
[α]20/D +13°, neat
自燃温度
761 °F
expl. lim.
9.8 %
折射率
n20/D 1.397 (lit.)
沸点
99-100 °C (lit.)
密度
0.803 g/mL at 25 °C (lit.)
官能团
hydroxyl
SMILES字符串
CC[C@H](C)O
InChI
1S/C4H10O/c1-3-4(2)5/h4-5H,3H2,1-2H3/t4-/m0/s1
InChI key
BTANRVKWQNVYAZ-BYPYZUCNSA-N
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应用
( S )-(+)-2-丁醇可用于:
- 合成手性不对称的聚对二甲苯二酰亚胺 (PDI),自发自组装成单手的光导 或荧光性质的纳米管。
- 合成体积庞大的手性乙烯基单体,可从根本上聚合成螺旋感过剩的螺旋聚合物。
- 作为手性溶剂研究了光敏酸 5,8-二氰-2-萘酚 (DCN2) 在手性环境中的激发态光转移。
应用
产品编号
说明
价格
警示用语:
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - STOT SE 3
靶器官
Central nervous system, Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
75.2 °F - closed cup
闪点(°C)
24 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Excited-state proton transfer in chiral environments. 1. Chiral solvents.
Solntsev KM, et al.
Journal of the American Chemical Society, 124(31), 9046-9047 (2002)
Highly fluorescent one-handed nanotubes assembled from a chiral asymmetric perylene diimide.
Ma X , et al.
Chemical Communications (Cambridge, England), 51(20), 4231-4233 (2015)
Stepwise Formation of Photoconductive Nanotubes through a New Top?Down Method.
Ma X , et al.
Advanced Materials, 27(47), 7746-7751 (2015)
Synthesis and characterization of optically active helical vinyl polymers via free radical polymerization.
Zhi J, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 47(9), 2408-2421 (2009)
Flaminia Rondino et al.
Physical chemistry chemical physics : PCCP, 13(3), 818-824 (2010-12-07)
Diastereomeric adducts between (S)-1-(4-fluorophenyl)-ethanol and R and S 2-butanol, formed by supersonic expansion, have been investigated by means of a combination of mass selected resonant two-photon ionization-spectroscopy and infrared depletion spectroscopy. Chiral recognition is evidenced by the specific spectroscopic signatures
Chromatograms
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