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蒸汽密度
3.7 (vs air)
质量水平
检测方案
≥99%
形式
liquid
折射率
n20/D 1.412 (lit.)
bp
102 °C (lit.)
mp
−89 °C (lit.)
溶解性
diethyl ether: miscible(lit.)
密度
1.026 g/mL at 25 °C (lit.)
SMILES字符串
CCCC(Cl)=O
InChI
1S/C4H7ClO/c1-2-3-4(5)6/h2-3H2,1H3
InChI key
DVECBJCOGJRVPX-UHFFFAOYSA-N
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一般描述
Photchlorination of butyryl chloride in liquid phase has been investigated.
应用
Butyryl chloride can be used as:
- A reagent in the acylation of thiophene in the liquid phase catalyzed by zeolites.
- A source of CO and -Cl in the chlorocarbonylation of aryl bromides to yield acid chlorides.
- An intermediate in the synthesis of aryl [11C]methylsulfones for PET applications.
警示用语：
Danger
危险分类
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
WGK
WGK 1
闪点(°F)
64.4 °F
闪点(°C)
18 °C
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
CHLORINATION OF BUTYRYL CHLORIDE IN THE LIQUID-PHASE.
Korhonen IO.
Acta Chemica Scandinavica. Series B, 35(3), 175-178 (1981)
A general method for the synthesis of aryl [11C] methylsulfones: potential PET probes for imaging cyclooxygenase-2 expression
Majo VJ, et al.
Bioorganic & Medicinal Chemistry Letters, 15(19), 4268-4271 (2005)
Palladium-catalyzed Chlorocarbonylation of Aryl (pseudo) Halides through in situ Generation of Carbon Monoxide
Boehm P, et al.
Angewandte Chemie (International Edition in English), 132(41), 18043-18052 (2020)
A lewis acid site-activated reaction in zeolites: thiophene acylation by butyryl chloride.
Isaev Y and Fripiat JJ.
J. Catal., 182(1), 257-263 (1999)
A Lewis acid site-activated reaction in zeolites: Thiophene acylation by butyryl chloride
Isaev Y and Fripiat JJ
J. Catal., 182(1), 257-263 (1999)
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