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Merck
CN

236306

Sigma-Aldrich

烯丙基氯

ReagentPlus®, 99%

别名:

3-氯-1-丙烯, 氯丙烯

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About This Item

线性分子式:
CH2=CHCH2Cl
CAS号:
分子量:
76.52
Beilstein:
635704
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽密度

2.6 (vs air)

质量水平

蒸汽压

20.58 psi ( 55 °C)
5.71 psi ( 20 °C)

产品线

ReagentPlus®

方案

99%

表单

liquid

expl. lim.

11.2 %

折射率

n20/D 1.414 (lit.)

沸点

44-46 °C (lit.)

mp

−130 °C (lit.)

溶解性

alcohol: miscible(lit.)
chloroform: miscible(lit.)
diethyl ether: miscible(lit.)
petroleum ether: miscible(lit.)
water: slightly soluble(lit.)

密度

0.939 g/mL at 25 °C (lit.)

官能团

alkyl halide
chloro

储存温度

2-8°C

SMILES字符串

ClCC=C

InChI

1S/C3H5Cl/c1-2-3-4/h2H,1,3H2

InChI key

OSDWBNJEKMUWAV-UHFFFAOYSA-N

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一般描述

氯丙烯与过氧化氢环氧化的动力学过程已有报道

应用

氯丙烯:
  • 已用作 193 nm 激光闪光光解产生烯丙基自由基的前体
  • 已用于 α,ω-双官能团化学中间体的合成(通过 交叉复分解反应)

法律信息

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

警示用语:

Danger

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Muta. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

靶器官

Nervous system,Liver,Kidney, Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(°F)

-25.6 °F

闪点(°C)

-32 °C

个人防护装备

Eyeshields, Faceshields, Gloves

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Lars Seidel et al.
Molecules (Basel, Switzerland), 18(11), 13608-13622 (2013-11-07)
Photochemically driven reactions involving unsaturated radicals produce a thick global layer of organic haze on Titan, Saturn's largest moon. The allyl radical self-reaction is an example for this type of chemistry and was examined at room temperature from an experimental
Epoxidation of allyl chloride with hydrogen peroxide catalyzed by titanium silicalite 1.
Gao H, et al.
Applied Catalysis A: General, 138(1), 27-38 (1996)
Cross-metathesis reactions of allyl chloride with fatty acid methyl esters: Efficient synthesis of a, ?-difunctional chemical intermediates from renewable raw materials.
Jacobs T, et al.
Applied Catalysis A: General, 353(1), 32-35 (2009)
Carbocycle synthesis through facile and efficient palladium-catalyzed allylative de-aromatization of naphthalene and phenanthrene allyl chlorides.
Shirong Lu et al.
Angewandte Chemie (International ed. in English), 47(23), 4366-4369 (2008-04-30)
B M de Rooij et al.
Drug metabolism and disposition: the biological fate of chemicals, 24(7), 765-772 (1996-07-01)
Allyl chloride (AC) is used as intermediate in the synthesis of epichlorohydrin (ECH). We investigated the biotransformation of AC in rats to select potential urinary biomarkers of exposure. For this purpose, we developed analytical methods to measure different selected urinary

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