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方案
97%
表单
chunks
mp
137-140 °C (lit.)
SMILES字符串
ClC(Cl)(Cl)S(Cl)(=O)=O
InChI
1S/CCl4O2S/c2-1(3,4)8(5,6)7
InChI key
ZCPSWAFANXCCOT-UHFFFAOYSA-N
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一般描述
Trichloromethanesulfonyl chloride is an efficient free radical chlorinating agent. It reacts with pent-4-enylcobaloximes in inert solvent under tugsten lamp irradiation to yield 2-(β,β,β- trichloroethyl)sulfolanes. It also reacts with trimethylsilyl enol ethers of acetophenones in the presence of a ruthenium (II) phosphine complex to yield 1-aryl-3,3-dichloropropen-1-one and α-chloroacetophenones.
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
Reactions of trichloromethanesulfonyl chloride and carbon tetrachloride with silyl enol ethers catalyzed by a ruthenium (II) phosphine complex.
Kamigata N, et al.
Journal of Organometallic Chemistry, 552(1), 9-43 (1998)
Homolytic displacement at saturated carbon. Part 9. The reactions of trichloromethanesulfonyl chloride with pent-4-enylcobaloximes and with olefins. A novel route to (trichloroethyl) sulfolanes via an SHi mechanism.
Ashcroft MR, et al.
The Journal of Organic Chemistry, 49(10), 1751-1761 (1984)
TRICHLOROMETHANESULFONYL CHLORIDE AS A SELECTIVE CHLORINATING AGENT1.
Huyser ES.
Journal of the American Chemical Society, 82(19), 5246-5247 (1960)
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