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质量水平
方案
99%
反应适用性
reaction type: Coupling Reactions
折射率
n20/D 1.428 (lit.)
沸点
48-50 °C/12 mmHg (lit.)
密度
0.8 g/mL at 25 °C (lit.)
应用
peptide synthesis
官能团
amine
SMILES字符串
CC(C)(C)N=C=NC(C)(C)C
InChI
1S/C9H18N2/c1-8(2,3)10-7-11-9(4,5)6/h1-6H3
InChI key
IDVWLLCLTVBSCS-UHFFFAOYSA-N
基因信息
human ... EPHX2(2053)
mouse ... Ephx2(13850)
应用
N,N′-Di-tert-butylcarbodiimide can be used:
- As a reagent for the guanylation of aryl amines catalyzed by lanthanum amides.
- To prepare dichloroimidazolidine-4,5-dione by reacting with oxalyl chloride, which is a key intermediate for the synthesis of N,N′-diamidocarbenes.
- To prepare the iridium complex of benzamidine named Ir(FMeppy)2(N,N′-di-tert-butyl-4-methyl-benzamidine).
警示用语：
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
95.0 °F - closed cup
闪点(°C)
35 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Qinghai Li et al.
The Journal of organic chemistry, 72(18), 6763-6767 (2007-08-07)
It is demonstrated that the cyclopentadienyl-free simple lanthanide amides [(Me(3)Si)(2)N](3)Ln(mu-Cl)Li(THF)(3)(Ln = La, Sm, Eu, Y, Yb) and Ln[N(SiMe(3))(2)]3 (Ln = Y, Yb) are highly efficient catalysts for the guanylation of both aromatic and secondary amines with a high activity under
Jonathan P Moerdyk et al.
Chemical communications (Cambridge, England), 50(35), 4551-4553 (2014-03-29)
The synthesis of the first stable, five-membered N,N'-diamidocarbenes (DACs), including a differentially N-substituted derivative, was achieved via the reduction of a geminal dichloride precursor using potassium. Key differences between the reactivity of the five-membered DACs and their six-membered congeners were
Synthesis, characterization and photophysical properties of iridium complexes with amidinate ligands
Sahin C, et al.
Journal of Organometallic Chemistry, 772, 68-78 (2014)
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