质量水平
检测方案
90%
折射率
n20/D 1.368 (lit.)
bp
61-63 °C (lit.)
溶解性
alcohol: very soluble(lit.)
carbon disulfide: very soluble(lit.)
chloroform: very soluble(lit.)
diethyl ether: very soluble(lit.)
glycerol: insoluble (practically)(lit.)
water: slightly soluble(lit.)
密度
0.867 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
CC(C)(C)ON=O
InChI
1S/C4H9NO2/c1-4(2,3)7-5-6/h1-3H3
InChI key
IOGXOCVLYRDXLW-UHFFFAOYSA-N
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一般描述
叔-亚硝酸丁酯（TBN）是一种有效的NO源。TBN参与将芳基和杂芳基胺通过光催化转化为硒化物。它还参与脂族烯烃的自由基多官能化反应。
应用
叔-亚硝酸丁酯已作为试剂：
- 用于醇、硫醇、胺和环烷烃的重氮化和亚硝化
- 用于使用芳基胺制备芳基叠氮化物
其他说明
残留物为 2-甲基-2-丙醇
警示用语：
Danger
危险声明
危险分类
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2
WGK
WGK 1
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
tert-Butyl Nitrite.
Liu Y.
Synlett, 2011(08), 1184-1185 (2011)
The Journal of Organic Chemistry, 42, 2426-2426 (1977)
The Journal of Organic Chemistry, 42, 3494-3494 (1977)
Daisuke Hirose et al.
Beilstein journal of organic chemistry, 9, 1713-1717 (2013-09-26)
Water induces a change in the product of radical multifunctionalization reactions of aliphatic alkenes involving an sp(3) C-H functionalization by an 1,5-hydrogen shift using tert-butyl nitrite and molecular oxygen. The reaction without water, reported previously, gives nitrated γ-lactols, whereas the
Debasish Kundu et al.
Organic letters, 16(6), 1814-1817 (2014-03-14)
A novel strategy for the direct conversion of aryl- and heteroarylamines to selenides has been developed via diazotization of amines with tert-butyl nitrite in neutral medium followed by reaction with diaryl/diheteroaryl/dialkyl diselenides in one pot under photocatalysis at room temperature
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