235385
亚硝酸叔丁酯
90%
别名:
1,1-Dimethylethyl nitrite
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关于此项目
线性分子式:
(CH3)3CONO
化学文摘社编号:
分子量:
103.12
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-757-0
Beilstein/REAXYS Number:
1209339
MDL number:
产品名称
亚硝酸叔丁酯, 90%
InChI key
IOGXOCVLYRDXLW-UHFFFAOYSA-N
InChI
1S/C4H9NO2/c1-4(2,3)7-5-6/h1-3H3
SMILES string
CC(C)(C)ON=O
assay
90%
refractive index
n20/D 1.368 (lit.)
bp
61-63 °C (lit.)
solubility
alcohol: very soluble(lit.)
carbon disulfide: very soluble(lit.)
chloroform: very soluble(lit.)
diethyl ether: very soluble(lit.)
glycerol: insoluble (practically)(lit.)
water: slightly soluble(lit.)
density
0.867 g/mL at 25 °C (lit.)
functional group
O-nitroso
nitroso
storage temp.
2-8°C
Quality Level
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Application
叔-亚硝酸丁酯已作为试剂：
- 用于醇、硫醇、胺和环烷烃的重氮化和亚硝化
- 用于使用芳基胺制备芳基叠氮化物
General description
叔-亚硝酸丁酯（TBN）是一种有效的NO源。TBN参与将芳基和杂芳基胺通过光催化转化为硒化物。它还参与脂族烯烃的自由基多官能化反应。
Other Notes
残留物为 2-甲基-2-丙醇
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
14.0 °F - closed cup
flash_point_c
-10 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
此项目有
Daisuke Hirose et al.
Beilstein journal of organic chemistry, 9, 1713-1717 (2013-09-26)
Water induces a change in the product of radical multifunctionalization reactions of aliphatic alkenes involving an sp(3) C-H functionalization by an 1,5-hydrogen shift using tert-butyl nitrite and molecular oxygen. The reaction without water, reported previously, gives nitrated γ-lactols, whereas the
tert-Butyl Nitrite.
Liu Y.
Synlett, 2011(08), 1184-1185 (2011)
The Journal of Organic Chemistry, 42, 2426-2426 (1977)
The Journal of Organic Chemistry, 42, 3494-3494 (1977)
The Journal of Organic Chemistry, 42, 2431-2431 (1977)
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