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质量水平
方案
97%
沸点
170 °C/0.5 mmHg (lit.)
mp
63-64 °C (lit.)
官能团
hydroxyl
thioether
SMILES字符串
OCCSCCSCCO
InChI
1S/C6H14O2S2/c7-1-3-9-5-6-10-4-2-8/h7-8H,1-6H2
InChI key
PDHFSBXFZGYBIP-UHFFFAOYSA-N
一般描述
3,6-二硫代-1,8-辛二醇是一种二级硫基催化剂毒剂。
应用
3,6-二硫代-1,8-辛二醇已用于：
- 作为外源螯合剂对膜可透过铜选择性荧光传感器进行评估，用于动态不稳定铜池的成像
- （+）-6-epi-粟树精胺和多羟基生物碱的不对称全合成
储存分类代码
11 - Combustible Solids
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Eric J Stoner et al.
The Journal of organic chemistry, 68(23), 8847-8852 (2003-11-08)
Functionalized erythromycin 9-oxime derivatives are 6-O-allylated under mild conditions using substituted allyl tert-butyl carbonates under palladium(0) catalysis. This allylation works well where traditional ether-forming protocols function poorly. Allyl tert-butyl carbonates provide higher yields in this reaction than lesser substituted carbonates
Liuchun Yang et al.
Proceedings of the National Academy of Sciences of the United States of America, 102(32), 11179-11184 (2005-08-03)
Copper is an essential micronutrient that plays a central role for a broad range of biological processes. Although there is compelling evidence that the intracellular milieu does not contain any free copper ions, the rapid kinetics of copper uptake and
Asymmetric Total Synthesis of (+)-6-epi-Castanospermine by the Stereoselective Formation of a syn, anti Acetylenic 2-Amino-1, 3-diol Stereotriad.
Louvel J, et al.
European Journal of Organic Chemistry, 2010(15), 2921-2926 (2010)
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