235229
二氯亚磷酸甲酯
technical grade
别名:
甲氧基二氯化膦
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关于此项目
线性分子式:
CH3OPCl2
化学文摘社编号:
分子量:
132.91
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
221-915-3
Beilstein/REAXYS Number:
1697452
MDL number:
Form:
liquid
InChI key
HCSDJECSMANTCX-UHFFFAOYSA-N
InChI
1S/CH3Cl2OP/c1-4-5(2)3/h1H3
SMILES string
COP(Cl)Cl
grade
technical grade
form
liquid
refractive index
n20/D 1.474 (lit.)
bp
93-95 °C (lit.)
mp
−91 °C (lit.)
density
1.376 g/mL at 20 °C (lit.)
Quality Level
Application
用于分别从亚磺酰氯和手性氨基醇合成硫代二氯磷酸酯以及氮氧杂膦烷。
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
77.0 °F - closed cup
flash_point_c
25 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Synthesis of deoxyoligonucleotides on a polymer support.
Matteucci MD and Caruthers MH.
Journal of the American Chemical Society, 103(11), 3181-3191 (1981)
Synthesis and enantioselective aldol reaction of a chiral 2-oxo-2-propionyl-1, 3, 2-oxazaphosphorinane.
Gordon NJ and Evans Jr SA.
The Journal of Organic Chemistry, 58(20), 5295-5297 (1993)
The Journal of Organic Chemistry, 58, 5295-5295 (1993)
Liming Zhang et al.
Journal of the American Chemical Society, 126(41), 13190-13191 (2004-10-14)
A highly efficient, two-step sequence method for the deoxygenation of hydroxyl groups has been developed. The method involves the preparation of the 2-(2-iodophenyl)ethyl methyl phosphite derivative of an alcohol using methyl dichlorophosphite and 2-(2-iodophenyl)ethanol. Treatment of the phosphite intermediate with
Synthetic Communications, 22, 289-289 (1992)
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