推荐产品
等级
technical grade
质量水平
表单
liquid
折射率
n20/D 1.474 (lit.)
沸点
93-95 °C (lit.)
mp
−91 °C (lit.)
密度
1.376 g/mL at 20 °C (lit.)
SMILES字符串
COP(Cl)Cl
InChI
1S/CH3Cl2OP/c1-4-5(2)3/h1H3
InChI key
HCSDJECSMANTCX-UHFFFAOYSA-N
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应用
用于分别从亚磺酰氯和手性氨基醇合成硫代二氯磷酸酯以及氮氧杂膦烷。
警示用语：
Danger
危险声明
危险分类
Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
补充剂危害
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
77.0 °F - closed cup
闪点(°C)
25 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Nanyan Fu et al.
Journal of peptide science : an official publication of the European Peptide Society, 12(4), 303-309 (2005-10-26)
A direct method for the preparation of phosphonamidate- and phosphonate-linked phosphonopeptides has been developed. Using this method, both phosphonopeptides were prepared in acceptable yields directly from simple and commercially available chemicals in one-pot reactions of benzyl carbamate, aldehydes, and methyl
Synthesis and enantioselective aldol reaction of a chiral 2-oxo-2-propionyl-1, 3, 2-oxazaphosphorinane.
Gordon NJ and Evans Jr SA.
The Journal of Organic Chemistry, 58(20), 5295-5297 (1993)
Synthesis of deoxyoligonucleotides on a polymer support.
Matteucci MD and Caruthers MH.
Journal of the American Chemical Society, 103(11), 3181-3191 (1981)
The Journal of Organic Chemistry, 58, 5295-5295 (1993)
Liming Zhang et al.
Journal of the American Chemical Society, 126(41), 13190-13191 (2004-10-14)
A highly efficient, two-step sequence method for the deoxygenation of hydroxyl groups has been developed. The method involves the preparation of the 2-(2-iodophenyl)ethyl methyl phosphite derivative of an alcohol using methyl dichlorophosphite and 2-(2-iodophenyl)ethanol. Treatment of the phosphite intermediate with
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