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Merck
CN

235229

Sigma-Aldrich

二氯亚磷酸甲酯

technical grade

别名:

甲氧基二氯化膦

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About This Item

线性分子式:
CH3OPCl2
CAS号:
分子量:
132.91
Beilstein:
1697452
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

等级

technical grade

质量水平

表单

liquid

折射率

n20/D 1.474 (lit.)

沸点

93-95 °C (lit.)

mp

−91 °C (lit.)

密度

1.376 g/mL at 20 °C (lit.)

SMILES字符串

COP(Cl)Cl

InChI

1S/CH3Cl2OP/c1-4-5(2)3/h1H3

InChI key

HCSDJECSMANTCX-UHFFFAOYSA-N

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应用

用于分别从亚磺酰氯和手性氨基醇合成硫代二氯磷酸酯以及氮氧杂膦烷

警示用语:

Danger

危险声明

危险分类

Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3

靶器官

Respiratory system

补充剂危害

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

77.0 °F - closed cup

闪点(°C)

25 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Synthesis and enantioselective aldol reaction of a chiral 2-oxo-2-propionyl-1, 3, 2-oxazaphosphorinane.
Gordon NJ and Evans Jr SA.
The Journal of Organic Chemistry, 58(20), 5295-5297 (1993)
Nanyan Fu et al.
Journal of peptide science : an official publication of the European Peptide Society, 12(4), 303-309 (2005-10-26)
A direct method for the preparation of phosphonamidate- and phosphonate-linked phosphonopeptides has been developed. Using this method, both phosphonopeptides were prepared in acceptable yields directly from simple and commercially available chemicals in one-pot reactions of benzyl carbamate, aldehydes, and methyl
Synthesis of deoxyoligonucleotides on a polymer support.
Matteucci MD and Caruthers MH.
Journal of the American Chemical Society, 103(11), 3181-3191 (1981)
T Tanaka et al.
Nucleic acids research, 10(10), 3249-3260 (1982-05-25)
A simple procedure is described for synthesis of oligonucleotides by phosphate chemistry. Chains can be constructed rapidly with minimal equipment (a syringe and reagent bottles). The method is illustrated by synthesis of d-TGCAGGTT. Pertinent supporting data on the effect of
The Journal of Organic Chemistry, 58, 5295-5295 (1993)

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