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About This Item
线性分子式:
BrCH2CO2Si(CH3)3
CAS号:
分子量:
211.13
Beilstein:
1927560
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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应用
Trimethylsilyl bromoacetate has been used:
- in the preparation of new imidazolium salts functionalized with the trimethylsilyl ester group
- as alkylating agent in the synthesis of succinate fragment of pantocin B (antibiotic natural product)
- in the synthesis of taxol derivatives tethered at C2′ and C-7 to glutamate and folate
警示用语：
Danger
危险声明
危险分类
Flam. Liq. 3 - Skin Corr. 1B
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
116.6 °F - closed cup
闪点(°C)
47 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
The [1, 2]-thio-Wittig rearrangement: evidence for a radical mechanism and its suppression.
Bertolli P, et al.
Tetrahedron Letters, 47(45), 7939-7942 (2006)
Copper and palladium complexes with N-heterocyclic carbene ligands functionalised with carboxylate groups.
Danopoulos AA, et al.
Journal of Organometallic Chemistry, 693(21), 3369-3374 (2008)
Jae Wook Lee et al.
Bioorganic & medicinal chemistry, 10(7), 2397-2414 (2002-05-02)
A series of Taxol derivatives tethered at C2' and C-7 to glutamate and folate have been synthesized for evaluation as prodrugs which release Taxol via hydrolytic lability of their alpha-alkoxy and alpha-amino esters. The half-time for hydrolysis of these materials
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